(a)
Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.
Concept Introduction: If 
, 
and 
groups are attached to the parent carbon, they are called primary, secondary and tertiary
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
To find: Assign the name for a given compound (a)
Categorize the number of alkyl groups attached to nitrogen atom
(b)
Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.
Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
To find: Assign the name for a given compound (b)
Categorize the number of alkyl groups attached to nitrogen atom
(c)
Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.
Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
To find: Assign the name for a given compound (c)
Categorize the number of alkyl groups attached to nitrogen atom
(d)
Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.
Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
To find: Assign the name for a given compound (d)
Categorize the number of alkyl groups attached to nitrogen atom
(e)
Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.
Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
To find: Assign the name for a given compound (e)
Categorize the number of alkyl groups attached to nitrogen atom
(f)
Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.
Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.
There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.
The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.
If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.
If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.
To find: Assign the name for a given compound (f)
Categorize the number of alkyl groups attached to nitrogen atom
Want to see the full answer?
Check out a sample textbook solution
Chapter 23 Solutions
Organic Chemistry, Binder Ready Version
- For a silver-silver chloride electrode, the following potentials are observed: E°cell = 0.222 V and E(saturated KCl) = 0.197 V Use this information to find the [Cl–] (technically it’s the activity of Cl– that’s relevant here, but we’ll just call it “concentration” for simplicity) in saturated KCl.arrow_forwardA concentration cell consists of two Sn/Sn2+ half-cells. The cell has a potential of 0.10 V at 25 °C. What is the ratio of [Sn2+] (i.e., [Sn2+left-half] / [Sn2+right-half])?arrow_forwardElectrochemical cell potentials can be used to determine equilibrium constants that would be otherwise difficult to determine because concentrations are small. What is Κ for the following balanced reaction if E˚ = +0.0218 V? 3 Zn(s) + 2 Cr3+(aq) → 3 Zn2+(aq) + Cr(s) E˚ = +0.0218 Varrow_forward
- Consider the following half-reactions: Hg2+(aq) + 2e– → Hg(l) E°red = +0.854 V Cu2+(aq) + 2e– → Cu(s)E°red = +0.337 V Ni2+(aq) + 2e– → Ni(s) E°red = -0.250 V Fe2+(aq) + 2e– → Fe(s) E°red = -0.440 V Zn2+(aq) + 2e– → Zn(s) E°red = -0.763 V What is the best oxidizing agent shown above (i.e., the substance that is most likely to be reduced)?arrow_forwardCalculate the equilibrium constant, K, for MnO2(s) + 4 H+(aq) + Zn(s) → Mn2+(aq) + 2 H2O(l) + Zn2+(aq)arrow_forwardIn the drawing area below, draw the condensed structures of formic acid and ethyl formate. You can draw the two molecules in any arrangement you like, so long as they don't touch. Click anywhere to draw the first atom of your structure. A C narrow_forward
- Write the complete common (not IUPAC) name of each molecule below. Note: if a molecule is one of a pair of enantiomers, be sure you start its name with D- or L- so we know which enantiomer it is. molecule Ο C=O common name (not the IUPAC name) H ☐ H3N CH₂OH 0- C=O H NH3 CH₂SH H3N ☐ ☐ X Garrow_forward(Part A) Provide structures of the FGI products and missing reagents (dashed box) 1 eq Na* H* H -H B1 B4 R1 H2 (gas) Lindlar's catalyst A1 Br2 MeOH H2 (gas) Lindlar's catalyst MeO. OMe C6H1402 B2 B3 A1 Product carbons' origins Draw a box around product C's that came from A1. Draw a dashed box around product C's that came from B1.arrow_forwardClassify each of the amino acids below. Note for advanced students: none of these amino acids are found in normal proteins. X CH2 H3N-CH-COOH3N-CH-COO- H3N-CH-COO CH2 CH3-C-CH3 CH2 NH3 N NH (Choose one) ▼ (Choose one) S CH2 OH (Choose one) ▼ + H3N-CH-COO¯ CH2 H3N CH COO H3N-CH-COO CH2 오오 CH CH3 CH2 + O C CH3 O= O_ (Choose one) (Choose one) ▼ (Choose one) Garrow_forward
- Another standard reference electrode is the standard calomel electrode: Hg2Cl2(s) (calomel) + 2e2 Hg() +2 Cl(aq) This electrode is usually constructed with saturated KCI to keep the Cl- concentration constant (similar to what we discussed with the Ag-AgCl electrode). Under these conditions the potential of this half-cell is 0.241 V. A measurement was taken by dipping a Cu wire and a saturated calomel electrode into a CuSO4 solution: saturated calomel electrode potentiometer copper wire CuSO4 a) Write the half reaction for the Cu electrode. b) Write the Nernst equation for the Cu electrode, which will include [Cu2+] c) If the voltage on the potentiometer reads 0.068 V, solve for [Cu²+].arrow_forward2. (Part B). Identify a sequence of FGI that prepares the Synthesis Target 2,4-dimethoxy- pentane. All carbons in the Synthesis Target must start as carbons in either ethyne, propyne or methanol. Hint: use your analysis of Product carbons' origins (Part A) to identify possible structure(s) of a precursor that can be converted to the Synthesis Target using one FGI. All carbons in the Synthesis Target must start as carbons in one of the three compounds below. H = -H H = -Me ethyne propyne Synthesis Target 2,4-dimethoxypentane MeOH methanol OMe OMe MeO. OMe C₂H₁₂O₂ Product carbons' origins Draw a box around product C's that came from A1. Draw a dashed box around product C's that came from B1.arrow_forwardDraw the skeletal ("line") structure of the smallest organic molecule that produces potassium 3-hydroxypropanoate when reacted with KOH. Click and drag to start drawing a structure. Sarrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY