Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 23, Problem 4LGP
Interpretation Introduction

Interpretation:

The structure of phospholipid, all the products which are formed from phospholipid on complete hydrolysis and the products of the given reactions with unsaturated fatty acid moiety of this phospholipid are to be drawn.

Concept Introduction:

▸ Phospholipids are a class of lipids which are a major component of all cell membranes.

▸ The structure of the phospholipid molecule consists of two hydrophobic fatty acids and a hydrophilic phosphate group. The two components are joined together by a glycerol molecule.

▸ Complete hydrolysis of a phospholipid gives two fatty acids (constituting the phospholipid), phosphoric acid and glycerol.

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A simple triacylglycerol is one that:   a) Upon hydrolysis produces glycerol and three different fatty acids. b) Upon hydrolysis produces glycerol and at least two different fatty acids. c) Upon saponification gives glycerol and three fatty acid salts. d) Upon saponification gives three esters. e) Upon hydrolysis produces glycerol and three mol of a fatty acid.
2
Explain briefly why sulfur mustard is soluble in the lipid bilayer membranes that surround human cells and in many fatty hydrocarbon polymers, while thiodiglycol used to synthesize sulfur mustard is less soluble in these hydrophobic materials and has greater solubility in water?
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