Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 23, Problem 2PP
Interpretation Introduction

Interpretation:

The isoprene units in the given compounds are to be shown and each of them as per their isoprene units are to be classified.

Concept introduction:

Essential oils are mixtures of odoriferous compounds that are extracted from plants by heating or steam distillation. These essential oils have important chemical composition of hydrocarbons called terpenes and oxygen-containing compounds called terpenoids.

A single isoprene unit consists of 5-carbon atoms with double bonds, and its chemical formula is 2methyl1,3butadiene. The structural formulae of isoprene and its single isoprene unit is as follows:

Organic Chemistry, Chapter 23, Problem 2PP

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Propose structure and give correct IUPAC names for the following: (a) A cyclic alkane with three methyl groups   (b) A diethyldimethylhexane
1. Explain the following observations: (i) Kevlar has an extremely high tensile strength and melting temperature.   (ii) At room temperature, poly(methylmethacrylate) is transparent, while polyethylene istranslucent. At temperatures above 135°C, both polymers are transparent.  (iii) Polyoxymethylene and polyethylene exhibit similar mechanical behaviour. However, the glass transition temperature of polyoxymethylene is about 50°C higher than that of polyethylene.
Answer Q18, 19, 20, 21
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