What parameters are included in the specific rotation calculation of a pure substancebased on measurement from a polarimeter?Select one or more:Density of the samplePathlength of the sample containerEnantiomeric excess of the sampleMeasured rotation of light

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Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry

Section: Chapter Questions

Problem 22.6QAP

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If a molecule contains stereocentres, is it guaranteed to be chiral?
Use the following character table for tetrahedral point group (To) to answer the following questions: Ta E 8C3 30 6S4 60d Ai +1 +1 +1 +1 +1 x²+y²+z² Az +1 +1 +1 -1 -1 E +2 -1 +2 0 0 (2x²-x²-y², x²-y²) T₁ +3 0 -1 +1 -1 (Rx, Ry, Rz) T₂ +3 0 -1 -1 +1 (x, y, z) (xy, xz, yz) (a) determine the orbitals symmetries of the central metal atom for tetrahedral metal complexes (ML4). (b) draw symmetry labelled molecular orbital (MO) diagram for ML4. Given that the ligand group orbitals (LGOs) symmetries are ai and tz. (c) clearly depict bonding, σ(a) and antibonding, o*(a1) MOs. + (d) use the above (part a) MO diagram to show the electron filling for tetrahedral [Ni(CO)4].
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1. Suggest 3 applications of Raman spectroscopy. 2. How polarizability is related to electric dipole moment? 3. How does the induced dipole moment occur? 4. Give the general parts of a Raman spectrophotometer. 5. Raman spectroscopy and infrared spectroscopy measures the vibrational frequencies of a molecule. List the differences between these two spectroscopic techniques.
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What parameters are included in the specific rotation calculation of a pure substance based on measurement from a polarimeter? Select one or more: Density of the sample Pathlength of the sample container Enantiomeric excess of the sample Measured rotation of light