(a) Interpretation: The mechanism of Staudinger reaction for preparation of given compound is to be stated. Concept Introduction: Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine . This reaction is known as the Staudinger reaction.

Question

Want to see the full answer?

Answer 1

Question

Chapter 23, Problem 23.81AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of Staudinger reaction for preparation of given compound is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(b)

Interpretation:

The mechanism for conversion of intermediate to probe labeled protein product is to be shown.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(c)

Interpretation:

In absence of methyl ester functional group, the product formed in the presence of water is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

A block of copper of mass 2.00kg(cp = 0.3851 .K) and g temperature 0°C is introduced into an insulated container in which there is 1.00molH, O(g) at 100°C and 1.00 2 atm. Note that C P = 4.184. K for liquid water, and g that A H = 2260 for water. vap g Assuming all the steam is condensed to water, and that the pressure remains constant: (a) What will be the final temperature of the system? (b) What is the heat transferred from the water to the copper? (c) What is the entropy change of the water, the copper, and the total system?

Identify the missing organic reactants in the following reaction: H+ X + Y OH H+ O O Note: This chemical equation only focuses on the important organic molecules in the reaction. Additional inorganic or small-molecule reactants or products (like H₂O) are not shown. In the drawing area below, draw the skeletal ("line") structures of the missing organic reactants X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Explanation Check Click and drag to start drawing a structure. X G 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Cente ? E

Calculate the solubility of CaF2 in g/L (Kp = 4.0 x 10-8). sp

Answer 2

Question

Chapter 23, Problem 23.81AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of Staudinger reaction for preparation of given compound is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(b)

Interpretation:

The mechanism for conversion of intermediate to probe labeled protein product is to be shown.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(c)

Interpretation:

In absence of methyl ester functional group, the product formed in the presence of water is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 23, Problem 23.81AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of Staudinger reaction for preparation of given compound is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(b)

Interpretation:

The mechanism for conversion of intermediate to probe labeled protein product is to be shown.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(c)

Interpretation:

In absence of methyl ester functional group, the product formed in the presence of water is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 23, Problem 23.81AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of Staudinger reaction for preparation of given compound is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(b)

Interpretation:

The mechanism for conversion of intermediate to probe labeled protein product is to be shown.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(c)

Interpretation:

In absence of methyl ester functional group, the product formed in the presence of water is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 23, Problem 23.81AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of Staudinger reaction for preparation of given compound is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(b)

Interpretation:

The mechanism for conversion of intermediate to probe labeled protein product is to be shown.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Interpretation Introduction

(c)

Interpretation:

In absence of methyl ester functional group, the product formed in the presence of water is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Answer 6

Chapter 23, Problem 23.81AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of Staudinger reaction for preparation of given compound is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Answer 7

Chapter 23, Problem 23.81AP

Interpretation Introduction

(a)

Interpretation:

The mechanism of Staudinger reaction for preparation of given compound is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water, iminophosphorane hydrolyses to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism for conversion of intermediate to probe labeled protein product is to be shown.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism for conversion of intermediate to probe labeled protein product is to be shown.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

In absence of methyl ester functional group, the product formed in the presence of water is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Answer 11

Interpretation Introduction

(c)

Interpretation:

In absence of methyl ester functional group, the product formed in the presence of water is to be stated.

Concept Introduction:

Reaction of alkyl halide with sodium azide gives alkyl azide. The alkyl azide reacts with triphenyl phosphine to form phosphazide. Phosphazide undergoes rearrangement reaction to form iminophosphorane. In presence of water iminophosphorane hydrolysed to give triphenylphosphine oxide and a primary amine. This reaction is known as the Staudinger reaction.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the mechanism of Staudinger reaction for preparation of given compound.

Want to see the full answer?

Chapter 23 Solutions