(a) Interpretation: Preparation of N - phenylbenzamide from an amine and an acid chloride is to be predicted. Concept introduction: The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 1

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.

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b. H3C CH3 1. 2. H3O+ H3C MgBr H3C

Answer 2

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 3

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 4

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 5

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 6

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 7

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the Schotten Baumann reaction, which is used to synthesise amides from amines and acid chlorides in the presence of a base.

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Chapter 23 Solutions