(a) Interpretation: The curved-arrow notation for the generation of nitrosyl cation, + N ¨ = O ¨ ¨ , from HNO 2 is to be stated. Concept introduction: Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

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Answer 1

Question

Chapter 23, Problem 23.34P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow notation for the generation of nitrosyl cation, +N¨=O¨¨, from HNO2 is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the electrophilic aromatic substitution reaction of N,N-dimethylaniline with HNO2 and HCl is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

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Answer 2

Question

Chapter 23, Problem 23.34P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow notation for the generation of nitrosyl cation, +N¨=O¨¨, from HNO2 is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the electrophilic aromatic substitution reaction of N,N-dimethylaniline with HNO2 and HCl is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

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Answer 3

Question

Chapter 23, Problem 23.34P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow notation for the generation of nitrosyl cation, +N¨=O¨¨, from HNO2 is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the electrophilic aromatic substitution reaction of N,N-dimethylaniline with HNO2 and HCl is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

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Answer 4

Question

Chapter 23, Problem 23.34P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow notation for the generation of nitrosyl cation, +N¨=O¨¨, from HNO2 is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the electrophilic aromatic substitution reaction of N,N-dimethylaniline with HNO2 and HCl is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

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Answer 5

Chapter 23, Problem 23.34P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow notation for the generation of nitrosyl cation, +N¨=O¨¨, from HNO2 is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the electrophilic aromatic substitution reaction of N,N-dimethylaniline with HNO2 and HCl is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Answer 6

Chapter 23, Problem 23.34P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow notation for the generation of nitrosyl cation, +N¨=O¨¨, from HNO2 is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Answer 7

Chapter 23, Problem 23.34P

Interpretation Introduction

(a)

Interpretation:

The curved-arrow notation for the generation of nitrosyl cation, +N¨=O¨¨, from HNO2 is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the electrophilic aromatic substitution reaction of N,N-dimethylaniline with HNO2 and HCl is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the electrophilic aromatic substitution reaction of N,N-dimethylaniline with HNO2 and HCl is to be stated.

Concept introduction:

Electrophilic aromatic substitution reaction involves the substitution of an electrophile on an aromatic ring. The π- bonds of an aromatic ring makes it electron rich which attracts an electron deficient electrophile towards itself and a substitution reaction takes place.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains how the curved-arrow notation for the generation of nitrosyl cation is shown.

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Chapter 23 Solutions