
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 22, Problem 2Q
Interpretation Introduction
Interpretation:
Monosaccharides that yield optically inactive alditol on
Concept introduction:
Alditols are the sugar alcohols formed by the reduction or the addition of hydrogen to the monosaccharides using sodium borohydride.
Carbohydrates containing simpler units of sugar molecule are called monosaccharides (mono means single and saccharide means sugar), which cannot be further hydrolysed into simpler carbohydrates.
Optically inactive compounds have an inability to rotate the plane of polarized light when the light is passed through the compound.
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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not
themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting
four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation
you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be
both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the
four structures.
Compound C
Possible conformations (circle one):
Дет
Lab Data
The distance entered is out of the expected range.
Check your calculations and conversion factors.
Verify your distance. Will the gas cloud be closer to the cotton ball with HCI or NH3?
Did you report your data to the correct number of significant figures?
- X
Experimental Set-up
HCI-NH3
NH3-HCI
Longer Tube
Time elapsed (min)
5 (exact)
5 (exact)
Distance between cotton balls (cm)
24.30
24.40
Distance to cloud (cm)
9.70
14.16
Distance traveled by HCI (cm)
9.70
9.80
Distance traveled by NH3 (cm)
14.60
14.50
Diffusion rate of HCI (cm/hr)
116
118
Diffusion rate of NH3 (cm/hr)
175.2
175.2
How to measure distance and calculate rate
For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically:
1:1 (one mole of EDTA per mole of metal ion)
2:1 (two moles of EDTA per mole of metal ion)
1:2 (one mole of EDTA per two moles of metal ion)
None of the above
Chapter 22 Solutions
Organic Chemistry
Ch. 22 - Prob. 1PPCh. 22 - Prob. 2PPCh. 22 - Prob. 3PPCh. 22 - Prob. 4PPCh. 22 - Prob. 5PPCh. 22 - Prob. 6PPCh. 22 - Prob. 7PPCh. 22 - Prob. 8PPCh. 22 - Practice Problem 22.9 What products would you...Ch. 22 - Prob. 10PP
Ch. 22 - Prob. 11PPCh. 22 - Prob. 12PPCh. 22 - Prob. 13PPCh. 22 - Prob. 14PPCh. 22 - Prob. 15PPCh. 22 - Prob. 16PPCh. 22 - Prob. 17PPCh. 22 - Prob. 18PPCh. 22 - Prob. 19PPCh. 22 - Prob. 20PCh. 22 - Prob. 21PCh. 22 - Prob. 22PCh. 22 - Prob. 23PCh. 22 - Prob. 24PCh. 22 - Prob. 25PCh. 22 - Prob. 26PCh. 22 - Prob. 27PCh. 22 - Prob. 28PCh. 22 - Prob. 29PCh. 22 - Prob. 30PCh. 22 - Prob. 31PCh. 22 - Prob. 32PCh. 22 - Prob. 33PCh. 22 - Prob. 34PCh. 22 - Prob. 35PCh. 22 - Prob. 36PCh. 22 - Prob. 37PCh. 22 - Prob. 38PCh. 22 - Arbutin, a compound that can be isolated from the...Ch. 22 - Prob. 40PCh. 22 - Prob. 41PCh. 22 - Prob. 42PCh. 22 - Prob. 43PCh. 22 - 22.44 The following reaction sequence represents...Ch. 22 - 22.45
The NMR data for the two anomers...Ch. 22 - Shikimic acid is a key biosynthetic intermediate...Ch. 22 - Prob. 1QCh. 22 - Prob. 2QCh. 22 - Give the structural formula of the monosaccharide...Ch. 22 - Prob. 4QCh. 22 - Prob. 5QCh. 22 - Prob. 6QCh. 22 - Prob. 7QCh. 22 - Prob. 8QCh. 22 - Select the reagent needed to perform the following...
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