(a) Interpretation: The structures for the major products of the given reactions are to be drawn. Concept introduction: When reagents such as HCl,HBr,and H 2 O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule. To determine: The structure for the major product of the given reaction.

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Answer 1

Question

Chapter 21, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

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Answer 2

Question

Chapter 21, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

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Answer 3

Question

Chapter 21, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

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Answer 4

Question

Chapter 21, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 6

Chapter 21, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 7

Chapter 21, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 12

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 13

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 14

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 15

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that the structures for the major products of the given reactions are to be drawn.

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Chapter 21 Solutions