The optically active non cyclic isomer of bromochloropropene is to be stated. Concept introduction: Isomers are defined as the organic compounds having the same molecular formula but different structural arrangement of atoms and optically active compounds are those which consist of a chiral carbon atom i.e. a carbon atom to which four different substituents are attached. The ability of an optically active compound to rotate the plane of polarized light is known as optical activity and they are commonly known as optical isomers. To determine: The optically active non cyclic isomer of Bromochloropropene.

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Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

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Chapter 21, Problem 103E

Interpretation Introduction

Interpretation: The optically active non cyclic isomer of bromochloropropene is to be stated.

Concept introduction: Isomers are defined as the organic compounds having the same molecular formula but different structural arrangement of atoms and optically active compounds are those which consist of a chiral carbon atom i.e. a carbon atom to which four different substituents are attached. The ability of an optically active compound to rotate the plane of polarized light is known as optical activity and they are commonly known as optical isomers.

To determine: The optically active non cyclic isomer of Bromochloropropene.

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Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

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