The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon. To determine: The name of the given cyclic alkane.

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Answer 1

Question

Chapter 21, Problem 139CWP

(a)

Interpretation The given cyclic alkanes are to be named.

Interpretation Introduction

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(b)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(c)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(d)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 21, Problem 139CWP

(a)

Interpretation The given cyclic alkanes are to be named.

Interpretation Introduction

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(b)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(c)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(d)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Expert Solution & Answer

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Answer 3

Question

Chapter 21, Problem 139CWP

(a)

Interpretation The given cyclic alkanes are to be named.

Interpretation Introduction

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(b)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(c)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(d)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 139CWP

(a)

Interpretation The given cyclic alkanes are to be named.

Interpretation Introduction

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(b)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(c)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(d)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 139CWP

(a)

Interpretation The given cyclic alkanes are to be named.

Interpretation Introduction

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(b)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(c)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

(d)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 6

Chapter 21, Problem 139CWP

(a)

Interpretation The given cyclic alkanes are to be named.

Interpretation Introduction

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 7

Chapter 21, Problem 139CWP

(a)

Interpretation The given cyclic alkanes are to be named.

Interpretation Introduction

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 8

(b)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 9

(b)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 10

(c)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 11

(c)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 12

(d)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 13

(d)

Interpretation Introduction

Interpretation The given cyclic alkanes are to be named.

Concept introduction: The IUPAC nomenclature of organic compound is a method used for naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC). Alkanes are saturated hydrocarbons and their names end by adding suffix –ane to the parent hydrocarbon. Cycloalkanes are cyclic hydrocarbons in which carbons are arranged in the ring. Therefore, they are named by adding prefix cyclo to the name of the hydrocarbon.

To determine: The name of the given cyclic alkane.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains the IUPAC nomenclature of organic compound, which is a method used for naming organic chemical compounds.

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