EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 8220100552236
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 21, Problem 30E
Interpretation Introduction
Interpretation: The systematic name for cumene is to be stated.
Concept introduction: Rules given by IUPAC should be followed to name an organic compound. Any organic compound that has only one name denotes that compound. The root word determines the number of carbons while counting the longest carbon chain. Naming of the compound is done according to the priorities of the
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 21 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQCh. 21 - Prob. 8RQCh. 21 - Prob. 9RQCh. 21 - Prob. 10RQ
Ch. 21 - Prob. 11RQCh. 21 - Prob. 12RQCh. 21 - Prob. 1QCh. 21 - Prob. 2QCh. 21 - What is wrong with the following names? Give the...Ch. 21 - Prob. 4QCh. 21 - Prob. 5QCh. 21 - Prob. 6QCh. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 12QCh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Draw all the structural isomers for C8H18 that...Ch. 21 - Draw all the structural isomers for C8H18 that...Ch. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Draw the structural formula for each of the...Ch. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Name each of the following alkenes. a. CH2 = CH ...Ch. 21 - Name each of the following alkenes or alkynes. a....Ch. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 21 - Prob. 32ECh. 21 - There is only one compound that is named...Ch. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Draw all structural and geometrical (cistrans)...Ch. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - If one hydrogen in a hydrocarbon is replaced by a...Ch. 21 - There are three isomers of dichlorobenzene, one of...Ch. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Minoxidil (C9H15N5O) is a compound produced by...Ch. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Name all the alcohols that have the formula...Ch. 21 - Prob. 54ECh. 21 - Prob. 55ECh. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Complete the following reactions. a. CH3CO2H +...Ch. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - The polyester formed from lactic acid, is used for...Ch. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Prob. 89ECh. 21 - Prob. 90ECh. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Prob. 94ECh. 21 - Prob. 95ECh. 21 - Prob. 96ECh. 21 - Prob. 97ECh. 21 - Prob. 98ECh. 21 - Prob. 99ECh. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Which base will hydrogen-bond with uracil within...Ch. 21 - Prob. 108ECh. 21 - The base sequences in mRNA that code for certain...Ch. 21 - Prob. 110ECh. 21 - Prob. 111AECh. 21 - Prob. 112AECh. 21 - Prob. 113AECh. 21 - Prob. 114AECh. 21 - Prob. 115AECh. 21 - Prob. 116AECh. 21 - Prob. 117AECh. 21 - Prob. 118AECh. 21 - Prob. 119AECh. 21 - Prob. 120AECh. 21 - Prob. 121AECh. 21 - Prob. 122AECh. 21 - Prob. 123AECh. 21 - Prob. 124AECh. 21 - Prob. 125AECh. 21 - Prob. 126AECh. 21 - Prob. 127AECh. 21 - Prob. 128AECh. 21 - Prob. 129AECh. 21 - Prob. 130AECh. 21 - Prob. 131AECh. 21 - Prob. 132AECh. 21 - Prob. 133AECh. 21 - Prob. 134AECh. 21 - When heat is added to proteins, the hydrogen...Ch. 21 - Prob. 136AECh. 21 - Prob. 137CWPCh. 21 - Prob. 138CWPCh. 21 - Prob. 139CWPCh. 21 - Name each of the following alkenes and alkynes. a....Ch. 21 - a. Name each of the following alcohols. b. Name...Ch. 21 - Prob. 142CWPCh. 21 - Prob. 143CWPCh. 21 - Prob. 144CWPCh. 21 - Prob. 145CPCh. 21 - Prob. 146CPCh. 21 - Prob. 147CPCh. 21 - Prob. 148CPCh. 21 - Prob. 149CPCh. 21 - Prob. 150CPCh. 21 - Prob. 151CPCh. 21 - Prob. 152CPCh. 21 - Prob. 153CPCh. 21 - Prob. 154CPCh. 21 - Stretch a rubber band while holding it gently to...Ch. 21 - Alcohols are very useful starting materials for...Ch. 21 - Prob. 157CPCh. 21 - Prob. 158CPCh. 21 - Prob. 159IPCh. 21 - Prob. 160IPCh. 21 - Prob. 161MPCh. 21 - Prob. 162MP
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