Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 21, Problem 36E
Interpretation Introduction

Interpretation: Ethers and alcohols needs to be explained as structural isomers using exampled. The functional group in the given table needs to be determined which is the structural isomer of carboxylic acids.

Concept introduction: When two or more molecules have the same formula but shows different properties, they are termed as isomers. Molecules having same molecular formula but arrangement of atoms is different in space are termed as structural isomers.

Expert Solution & Answer
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Answer to Problem 36E

Ethers and alcohols are the structural isomers of one another which can be illustrated by considering a molecular formula C3H8O . Alcohol and ether can be drawn from the same molecular formula, C3H8O as:

  Chemical Principles, Chapter 21, Problem 36E , additional homework tip  1

Aldehydes and ketones are the structural isomers of one another which can be illustrated by considering a molecular formula C4H8O . Aldehyde and ketone can be drawn from the same molecular formula, C4H8O as:

  Chemical Principles, Chapter 21, Problem 36E , additional homework tip  2

From the given table, esters are the structural isomers of carboxylic acids.

Explanation of Solution

Given information:

    ClassFunctional GroupGeneral FormulaExample
    Halohaydrocarbon−X (F, Cl, Br, I)R−XCH3I Iodomethane (methyl iodide)
    Alcohols−OHR−OHCH3OH Methanol (methyl alcohol)
    Ethers−O−R−O−RCH3OCH3 Dimethyl ether
    AldehydesChemical Principles, Chapter 21, Problem 36E , additional homework tip  3Chemical Principles, Chapter 21, Problem 36E , additional homework tip  4CH3O Methanal (Formaldehyde)
    KetonesChemical Principles, Chapter 21, Problem 36E , additional homework tip  5Chemical Principles, Chapter 21, Problem 36E , additional homework tip  6CH3COCH3 Propanone (Dimethyl ketone or acetone)
    Carboxylic acidsChemical Principles, Chapter 21, Problem 36E , additional homework tip  7Chemical Principles, Chapter 21, Problem 36E , additional homework tip  8CH3COOH Ethanoic acid (acetic acid)
    EstersChemical Principles, Chapter 21, Problem 36E , additional homework tip  9Chemical Principles, Chapter 21, Problem 36E , additional homework tip  10CH3COOCH2CH3 Ethyl acetate
    AminesNH2RNH2CH3NH2 Aminomethane (methylamine)

Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Ethers and alcohols are the structural isomers of each other which can be illustrated by considering a molecular formula C3H8O . Alcohol and ether can be drawn from the same molecular formula, C3H8O as:

  Chemical Principles, Chapter 21, Problem 36E , additional homework tip  11

Aldehydes and ketones are the structural isomers of one another which can be illustrated by considering a molecular formula C4H8O . Aldehyde and ketone can be drawn from the same molecular formula, C4H8O as:

  Chemical Principles, Chapter 21, Problem 36E , additional homework tip  12

From the given table, esters are the structural isomers of carboxylic acids which can be illustrated by considering a molecular formula C2H4O2 . Carboxylic acid and ester can be drawn from the same molecular formula, C2H4O2 as:

  Chemical Principles, Chapter 21, Problem 36E , additional homework tip  13

Conclusion

Ethers and alcohols are the structural isomers of each other which can be illustrated by considering a molecular formula C3H8O . Alcohol and ether can be drawn from the same molecular formula, C3H8O as:

  Chemical Principles, Chapter 21, Problem 36E , additional homework tip  14

Aldehydes and ketones are the structural isomers of one another which can be illustrated by considering a molecular formula C4H8O . Aldehyde and ketone can be drawn from the same molecular formula, C4H8O as:

  Chemical Principles, Chapter 21, Problem 36E , additional homework tip  15

From the given table, esters are the structural isomers of carboxylic acids.

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Chapter 21 Solutions

Chemical Principles

Ch. 21 - Prob. 11ECh. 21 - Name each of the following cyclic alkanes, and...Ch. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Name the following compounds.Ch. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Draw structural formulas for each of the following...Ch. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - Prob. 55ECh. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Give an example reaction that would yield the...Ch. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - Prob. 76ECh. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Prob. 89ECh. 21 - Prob. 90ECh. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Prob. 94ECh. 21 - Prob. 95ECh. 21 - Draw the structures of the tripeptides gly-ala-ser...Ch. 21 - Prob. 97ECh. 21 - Prob. 98ECh. 21 - What types of interactions can occur between the...Ch. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Prob. 107ECh. 21 - Prob. 108ECh. 21 - Prob. 109ECh. 21 - Prob. 110ECh. 21 - Prob. 111ECh. 21 - Prob. 112ECh. 21 - Prob. 113ECh. 21 - Prob. 114ECh. 21 - Prob. 115ECh. 21 - Prob. 116ECh. 21 - Prob. 117ECh. 21 - Prob. 118ECh. 21 - Prob. 119ECh. 21 - Prob. 120ECh. 21 - Prob. 121ECh. 21 - Prob. 122ECh. 21 - Prob. 123ECh. 21 - Prob. 124ECh. 21 - Prob. 125ECh. 21 - Prob. 126ECh. 21 - Prob. 127AECh. 21 - Prob. 128AECh. 21 - Prob. 129AECh. 21 - Prob. 130AECh. 21 - Prob. 131AECh. 21 - Prob. 132AECh. 21 - Prob. 133AECh. 21 - Prob. 134AECh. 21 - Prob. 135AECh. 21 - Prob. 136AECh. 21 - Prob. 137AECh. 21 - Prob. 138AECh. 21 - Prob. 139AECh. 21 - Prob. 140AECh. 21 - Prob. 141AECh. 21 - Prob. 142AECh. 21 - Prob. 143AECh. 21 - Prob. 144AECh. 21 - Prob. 145AECh. 21 - Prob. 146AECh. 21 - Prob. 147AECh. 21 - Prob. 148AECh. 21 - Prob. 149AECh. 21 - Prob. 150AECh. 21 - Prob. 151AECh. 21 - Prob. 152AECh. 21 - Prob. 153AECh. 21 - Prob. 154AECh. 21 - Prob. 155AECh. 21 - Prob. 156AECh. 21 - Prob. 157AECh. 21 - Prob. 158AECh. 21 - Prob. 159AECh. 21 - Prob. 160AECh. 21 - Prob. 161AECh. 21 - Name each of the following cyclic alkanes.Ch. 21 - Prob. 163AECh. 21 - Prob. 164AECh. 21 - Prob. 165AECh. 21 - Prob. 166AECh. 21 - Prob. 167AECh. 21 - Prob. 168AECh. 21 - Prob. 169CPCh. 21 - Prob. 170CPCh. 21 - Prob. 171CPCh. 21 - Prob. 172CPCh. 21 - Prob. 173CPCh. 21 - Prob. 174CP
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