Concept explainers
(a)
Interpretation: The structure of the product of the following reaction needs to be determined.
Concept Introduction : The addition of oxygen to a compound is called oxidation. The oxidation of conpounds can be done by many reagents like potassium nitrate, nitric acid, potassium permanganate etc.
(b)
Interpretation: The structure of the product of the following reaction needs to be determined.
Concept Introduction : The addition of oxygen to a compound is called oxidation. The oxidation of conpounds can be done by many reagents like potassium nitrate, nitric acid, potassium permanganate etc.
(c)
Interpretation: The product of the following reaction needs to be determined.
Concept Introduction : The addition of oxygen to a compound is called oxidation. The oxidation of conpounds can be done by many reagents like potassium nitrate, nitric acid, potassium permanganate etc.
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Chapter 21 Solutions
Chemical Principles
- Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise 62.) (Hint: In the presence of H+, an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. 1-butanol butane b. 1-butanol 2-butanonearrow_forwardWhat are the major products of the reaction of ethyl benzoate with hydrochloric acid and water? a. acetic acid and toluene b. phenylic acid and ethanol C. ethanoic acid and benzene d. benzoic acid and ethanol e. phenylic acid and methanol O a O barrow_forwardWhat are the major products of the reaction of ethyl benzoate with hydrochloric acid and water? a. benzoic acid and ethanol b. phenylic acid and ethanol c. ethanoic acid and benzene d. acetic acid and toluene e. phenylic acid and methanolarrow_forward
- Which of the following organic compounds has a functional group of a carboxyl group?A. alkyl halide B. ester C. ketone D. aminearrow_forwardIn an esterification reaction, a carboxylic acid reacts with an excess of alcohol in acidic conditions to form an ester. Draw the structure of the ester product in the reaction between pentanoic acid and 1‑propanol.arrow_forward1. What functional group is produced when an aldehyde reacts with H2/Pt? A.secondary alcohol B. carboxylic acid C.hemiacetal D. primary alcohol E.alkane F.tertiary alcohol G. alkene 2. What reaction occurs when an aldehyde reacts with H2/Pt to form a primary alcohol? A. Hydration B. Hydration C. Dehydration D. Oxidation E. Reduction( hydrogentation) 3. What reaction occurs when an Ester react with H+/H2O to from a carboxylic acid and alcohol? A. Dehydration B. Reduction ( Hydrogenation) C.Hydrolysis D. Hydration E.oxidationarrow_forward
- 23. What reactant and catalyst is(are) needed to change ethene into ethane? a. H2, Pt b. H2O, H2SO4 c. HCI d. heat, pressurearrow_forwardIdentify the organic functional group of the reactant and the reaction type then predict the functional group(s) of the product(s).The reactant is a(n)a. ketoneb. esterc. amided. alcohole. carboxylic acidf. amineg. aldehydeThe reaction type isa. hydrationb. hydrolysis (in base)c. esterificationd. dehydratione. hydrolysis (in acid)f. amide synthesisThe product should be a(n)a. ketoneb. aldehydec. alcohol onlyd. estere. carboxylic acid and an alcoholf. carboxylic acid onlyg. amidearrow_forwardThe C=O linkage occurs in molecules with the following functional groups EXCEPT a. esters b. carboxylic acids c. aldehydes d. amines e. ketonesarrow_forward
- Identify the organic functional groups and reaction type for the following reaction.The reactant is a(n)a. secondary amideb. carboxylic acidc. tertiary amided. aromatice. ketonef. primary amideg. aldehydeh. amineThe products are a(n)a. carboxylate ion and amineb. ketone and aminec. carboxylic acid and amided. carboxylic acid and alcohole. ester and aminef. aldehyde and amineg. carboxylic acid and ammonium ionThe reaction type isa. hydrolysis (in acid)b. amide synthesisc. hydrationd. esterificatione. dehydrationf. hydrolysis (in base)arrow_forwardHow does the structure of an alcohol differ from an ether? Describe how an aldehyde differs in structure from a ketone. Thiols are compounds which resemble alcohols, except that the oxygen atom is replaced by a sulfur atom. Draw the analogous thiol for the four carbon alcohol in Table 1. Describe the structural difference between carboxylic acids and esters. Are ethers polar molecules? Would you expect ethers to have higher or lower boiling points than alkanes (circle one)? Explain. Pentane (an alkane) has a boiling point of 36 °C. Does the data agree with your prediction? explain why this could be the casearrow_forwardName the type of organic compound formed by each ofthe following reactions.a. elimination from an alcoholb. addition of hydrogen chloride to an alkenec. addition of water to an alkened. substitution of a hydroxyl group for a halogen atomarrow_forward
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