Concept explainers
(a)
Interpretation: The reason for 2-chloro-2-butyne to not exist needs to be explained.
Concept Introduction : Carbon is tetravalent this means that carbon has a valency of four. Carbon can accommodate four atoms. A compound cannot exist without satisfying the Carbon valency of four.
(b)
Interpretation: The reason for 2-methyl-2-propanone to not exist needs to be explained.
Concept Introduction : Carbon is tetravalent. This means that Carbon has a valency of four. Carbon can accommodate four atoms. A compound cannot exist without satisfying the Carbon valency of four.
(c)
Interpretation: The reason for 1,1-dimethylbenzene to not exist needs to be explained.
Concept Introduction : Carbon is tetravalent, this means that Carbon has a valency of four. Carbon can accommodate four atoms. A compound cannot exist without satisfying the Carbon valency of four.
(d)
Interpretation: The reason due to which 2-pentanal cannot exist needs to be explained.
Concept Introduction: Carbon is tetravalent means that Carbon has a valency of four. Carbon can accommodate four atoms. A compound cannot exist without satisfying the Carbon valency of four.
(e)
Interpretation: The reason due to which 3-hexanoic acid does not exist needs to be determined.
Concept Introduction: Carbon is tetravalent. This means that Carbon has a valency of four. Carbon can accommodate four atoms. A compound cannot exist without satisfying the Carbon valency of four.
(f)
Interpretation: The reason due to which 5,5-dibromo-1-cyclobutanol does not exist needs to be determined.
Concept Introduction: Carbon is tetravalent. This means that Carbon has a valency of four. Carbon can accommodate four atoms. A compound cannot exist without satisfying the Carbon valency of four.
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Chemical Principles
- Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise 62.) (Hint: In the presence of H+, an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. 1-butanol butane b. 1-butanol 2-butanonearrow_forwardWhich is not a structural isomer of hexyne. a. 2-hexyne b. 3-hexyne c. 2,2-dimethylpentane d. 4-methyl-1-pentyne e. 2,3 - dimethylbutane.arrow_forwardHO The IUPAC name for the line structural diagram shown above is O a. 1,5-pentanediol O b. pentane-1,5-diol O c. heptane-1,7-diol The organic compound shown in Question 7 is classified as a(n) O a. alcohol O b. carboxylic acid O c. ester Od. halogenated hydrocarbon The organic compound shown in Question 7 contains which functional group? O a. carboxyl O b. ester linkage O c. halogen Od. hydroxyl OH A student wrote the condensed formula shown below: CH₂CH₂COOH The IUPAC name for this condensed formula is: O a. propanol O b. ethanoic acid O c. propanoic acid O d. propanoate The organic compound in Question 10 is classified as a(n) Select one: O alcohol Oester O halogenated hydrocarbon O carboxylic acid The organic compound in Question 10 contains which functional group? Select one: O halogen O carboxyl Oester linkage O hydroxylarrow_forward
- Draw the structural formulas for each of the following organic compounds. Circle the non- alkyl functional groups a. hexan-2-one b. 2- methylpentanal c. Pentane-1,3-diol d. buta-1,3-diene e. 1-propoxybutane f. ethyl ethanoatearrow_forwardA student was given the structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed. a. 4-bromo-3-pentanol b. 2,2-dimethyl-4-ethylheptane c. 5-methylcyclohexanol d. 1,1-dimethyl-2-cyclohexanol e. 5-(2,2-dimethylethyl)nonane f. isopentylbromide g. 3,3-dichlorooctane h. 5-ethyl-2-methylhexane i. 1-bromo-4-pentanol j. 3-isopropyloctane k. 2-methyl-2-isopropylheptane l. 2-methyl-N,N-dimethyl-4-hexanaminearrow_forward1. Draw a simple organic molecule that contain the following functional groups. a. Cycloalkane d. Ester b. Amine c. Ether e. Aldehyde f. Ketonearrow_forward
- Does cis/trans-isomerism exists in? a.3-methyl-1-pentene b.2-methyl-2-butene c.1,2-dichloroethenearrow_forwardName the organic compound below A. 2,2,4-trimethyl-3-hexene B. 2,3,3-trimethyl-2-hexene C. 2,2,4-trimethyl-3-hexyne D. 2,3,3-trimethyl-2-hexynearrow_forwardDraw structures for the following molecules.a. 2-chlorobutane c. 1,1,1-trichloroethaneb. 1,3-difluorohexane d. 4-bromo-1-chlorobenzenearrow_forward
- Draw the condensed structural formula of the following organic compounds and label the carbon atoms.arrow_forwardDraw the structures of the following hydrocarbon derivatives. a. Butyl heptanoate b. 3-chloro-4-ethylbenzoic acid c. N,N-diethylpent-3-en-1-amine d. 4-methoxyhept-2-ene e. 3-ethyl-N,2-dimethylhexan-1-amidearrow_forwardHow would you synthesize each of the following?a. 1,2-dibromopropane from propeneb. acetone (2-propanone) from an alcoholc. tert-butyl alcohol (2-methyl-2-propanol) from an alkene (See Exercise 62.)d. propanoic acid from an alcoholarrow_forward
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