The four structures having same physical properties like boiling point, melting point, density etc needs to be determined. Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Question

a) 5. Circle all acidic (and anticoplanar to the Leaving group) protons in the following molecules, Solve these elimination reactions, and identify the major and minor products where appropriate: 20 points + NaOCH3 Br (2 product

Answer 1

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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a) 5. Circle all acidic (and anticoplanar to the Leaving group) protons in the following molecules, Solve these elimination reactions, and identify the major and minor products where appropriate: 20 points + NaOCH3 Br (2 product

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Dr. Mendel asked his BIOL 260 class what their height was and what their parent's heights were. He plotted that data in the graph below to determine if height was a heritable trait. A. Is height a heritable trait? If yes, what is the heritability value? (2 pts) B. If the phenotypic variation is 30, what is the variation due to additive alleles? (2 pts) Offspring Height (Inches) 75 67.5 60 52.5 y = 0.9264x + 4.8519 55 60 65 MidParent Height (Inches) 70 75 12pt v V Paragraph B IUA > AT2 v V

Answer 2

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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Answer 3

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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Answer 4

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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Answer 5

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 6

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 7

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 12

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Answer 23

Ch. 21 - Prob. 1E Ch. 21 - Prob. 2E Ch. 21 - Why are cyclopropane and cyclobutane so reactive?Ch. 21 - Prob. 4E Ch. 21 - Prob. 5E Ch. 21 - Prob. 6E Ch. 21 - Prob. 7E Ch. 21 - Name the five structural isomers of C6H14 .Ch. 21 - Draw the structural formula for each of the...Ch. 21 - Prob. 10E

Solution Summary: The author explains Cis-trans isomerism, which occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups.

Chapter 21 Solutions