a) LiAlH 4 , then H 3 O + Interpretation: The product produced when p-methylbenzoic acid is treated with LiAlH 4 and then with H 3 O + is to be predicted. Concept introduction: Carboxylic acids get reduced to primary alcohols when treated with LiAlH 4 . To predict: The product produced when p-methylbenzoic acid is treated with LiAlH 4 and then with H 3 O + .

Question

Draw product A, indicating what type of reaction occurs. NH2 F3C CF3 NH OMe NH2-NH2, ACOH A

Answer 1

Question

Chapter 20.SE, Problem 47AP

Interpretation Introduction

a) LiAlH₄, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺ is to be predicted.

Concept introduction:

Carboxylic acids get reduced to primary alcohols when treated with LiAlH₄.

To predict:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺.

Interpretation Introduction

b) N-Bromosuccinimide in CCl₄

Interpretation:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄ is to be predicted.

Concept introduction:

N-bromosuccinimide in CCl₄ is used for introducing a Br in the benzyl carbon.

To predict:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄.

Interpretation Introduction

c) CH₃MgBr in ether, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺ is to be predicted.

Concept introduction:

Grignard reagents will react with the carboxyl hydrogen to yield alkanes.

To predict:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺.

Interpretation Introduction

d) KMnO₄, H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺ is to be predicted.

Concept introduction:

When treated with KMnO₄ in the presence of H₃O⁺, the side chain in aromatic compounds is oxidized to carboxyl group.

To predict:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

Draw product A, indicating what type of reaction occurs. NH2 F3C CF3 NH OMe NH2-NH2, ACOH A

Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Correct each molecule in the drawing area below so that it has the skeletal ("line") structure it would have if it were dissolved in a 0.1 M aqueous solution of HCI. If there are no changes to be made, check the No changes box under the drawing area. No changes. HO Explanation Check NH, 2 W O :□ G ©2025 M unter Accessibility

Answer 2

Question

Chapter 20.SE, Problem 47AP

Interpretation Introduction

a) LiAlH₄, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺ is to be predicted.

Concept introduction:

Carboxylic acids get reduced to primary alcohols when treated with LiAlH₄.

To predict:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺.

Interpretation Introduction

b) N-Bromosuccinimide in CCl₄

Interpretation:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄ is to be predicted.

Concept introduction:

N-bromosuccinimide in CCl₄ is used for introducing a Br in the benzyl carbon.

To predict:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄.

Interpretation Introduction

c) CH₃MgBr in ether, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺ is to be predicted.

Concept introduction:

Grignard reagents will react with the carboxyl hydrogen to yield alkanes.

To predict:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺.

Interpretation Introduction

d) KMnO₄, H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺ is to be predicted.

Concept introduction:

When treated with KMnO₄ in the presence of H₃O⁺, the side chain in aromatic compounds is oxidized to carboxyl group.

To predict:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 20.SE, Problem 47AP

Interpretation Introduction

a) LiAlH₄, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺ is to be predicted.

Concept introduction:

Carboxylic acids get reduced to primary alcohols when treated with LiAlH₄.

To predict:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺.

Interpretation Introduction

b) N-Bromosuccinimide in CCl₄

Interpretation:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄ is to be predicted.

Concept introduction:

N-bromosuccinimide in CCl₄ is used for introducing a Br in the benzyl carbon.

To predict:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄.

Interpretation Introduction

c) CH₃MgBr in ether, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺ is to be predicted.

Concept introduction:

Grignard reagents will react with the carboxyl hydrogen to yield alkanes.

To predict:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺.

Interpretation Introduction

d) KMnO₄, H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺ is to be predicted.

Concept introduction:

When treated with KMnO₄ in the presence of H₃O⁺, the side chain in aromatic compounds is oxidized to carboxyl group.

To predict:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 20.SE, Problem 47AP

Interpretation Introduction

a) LiAlH₄, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺ is to be predicted.

Concept introduction:

Carboxylic acids get reduced to primary alcohols when treated with LiAlH₄.

To predict:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺.

Interpretation Introduction

b) N-Bromosuccinimide in CCl₄

Interpretation:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄ is to be predicted.

Concept introduction:

N-bromosuccinimide in CCl₄ is used for introducing a Br in the benzyl carbon.

To predict:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄.

Interpretation Introduction

c) CH₃MgBr in ether, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺ is to be predicted.

Concept introduction:

Grignard reagents will react with the carboxyl hydrogen to yield alkanes.

To predict:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺.

Interpretation Introduction

d) KMnO₄, H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺ is to be predicted.

Concept introduction:

When treated with KMnO₄ in the presence of H₃O⁺, the side chain in aromatic compounds is oxidized to carboxyl group.

To predict:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 20.SE, Problem 47AP

Interpretation Introduction

a) LiAlH₄, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺ is to be predicted.

Concept introduction:

Carboxylic acids get reduced to primary alcohols when treated with LiAlH₄.

To predict:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺.

Interpretation Introduction

b) N-Bromosuccinimide in CCl₄

Interpretation:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄ is to be predicted.

Concept introduction:

N-bromosuccinimide in CCl₄ is used for introducing a Br in the benzyl carbon.

To predict:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄.

Interpretation Introduction

c) CH₃MgBr in ether, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺ is to be predicted.

Concept introduction:

Grignard reagents will react with the carboxyl hydrogen to yield alkanes.

To predict:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺.

Interpretation Introduction

d) KMnO₄, H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺ is to be predicted.

Concept introduction:

When treated with KMnO₄ in the presence of H₃O⁺, the side chain in aromatic compounds is oxidized to carboxyl group.

To predict:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺.

Answer 6

Chapter 20.SE, Problem 47AP

Interpretation Introduction

a) LiAlH₄, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺ is to be predicted.

Concept introduction:

Carboxylic acids get reduced to primary alcohols when treated with LiAlH₄.

To predict:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺.

Answer 7

Chapter 20.SE, Problem 47AP

Interpretation Introduction

a) LiAlH₄, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺ is to be predicted.

Concept introduction:

Carboxylic acids get reduced to primary alcohols when treated with LiAlH₄.

To predict:

The product produced when p-methylbenzoic acid is treated with LiAlH₄ and then with H₃O⁺.

Answer 8

Interpretation Introduction

b) N-Bromosuccinimide in CCl₄

Interpretation:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄ is to be predicted.

Concept introduction:

N-bromosuccinimide in CCl₄ is used for introducing a Br in the benzyl carbon.

To predict:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄.

Answer 9

Interpretation Introduction

b) N-Bromosuccinimide in CCl₄

Interpretation:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄ is to be predicted.

Concept introduction:

N-bromosuccinimide in CCl₄ is used for introducing a Br in the benzyl carbon.

To predict:

The product produced when p-methylbenzoic acid is treated with N-bromosuccinimide in CCl₄.

Answer 10

Interpretation Introduction

c) CH₃MgBr in ether, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺ is to be predicted.

Concept introduction:

Grignard reagents will react with the carboxyl hydrogen to yield alkanes.

To predict:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺.

Answer 11

Interpretation Introduction

c) CH₃MgBr in ether, then H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺ is to be predicted.

Concept introduction:

Grignard reagents will react with the carboxyl hydrogen to yield alkanes.

To predict:

The product produced when p-methylbenzoic acid is treated with CH₃MgBr and then with H₃O⁺.

Answer 12

Interpretation Introduction

d) KMnO₄, H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺ is to be predicted.

Concept introduction:

When treated with KMnO₄ in the presence of H₃O⁺, the side chain in aromatic compounds is oxidized to carboxyl group.

To predict:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺.

Answer 13

Interpretation Introduction

d) KMnO₄, H₃O⁺

Interpretation:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺ is to be predicted.

Concept introduction:

When treated with KMnO₄ in the presence of H₃O⁺, the side chain in aromatic compounds is oxidized to carboxyl group.

To predict:

The product produced when p-methylbenzoic acid is treated with KMnO₄ in the presence of H₃O⁺.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 17

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 18

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 19

Trending nowThis is a popular solution!

Answer 20

Trending nowThis is a popular solution!

Answer 21

Trending nowThis is a popular solution!

Answer 22

Trending now

Answer 23

This is a popular solution!

Answer 24

See solution

Check out sample textbook solution

Answer 25

Ch. 20.1 - Give IUPAC names for the following compounds:Ch. 20.1 - Draw structures corresponding to the following...Ch. 20.2 - Prob. 3P Ch. 20.2 - The Ka for dichloroacetic acid is 3.32 Ă— 10-2....Ch. 20.3 - Calculate the percentages of dissociated and...Ch. 20.4 - Which would you expect to be a stronger acid, the...Ch. 20.4 - Dicarboxylic acids have two dissociation...Ch. 20.4 - The pKa of p-cyclopropylbenzoic acid is 4.45. Is...Ch. 20.4 - Prob. 9P Ch. 20.5 - Prob. 10P

Chapter 20 Solutions