a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide Interpretation: Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity. Concept introduction: The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed. To arrange: Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Question

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

Answer 1

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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In an experiment, the viscosity of water was measured at different temperatures and the table was constructed from the data obtained. a) Calculate the activation energy of viscous flow (kJ/mol). b) Calculate the viscosity at 30°C. T/°C 0 20 40 60 80 η/cpoise 1,972 1,005 0,656 0,469 0,356

Answer 2

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 3

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 4

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 5

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 6

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Answer 7

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Answer 8

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Answer 9

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Answer 10

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 11

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 12

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Answer 23

Ch. 20.1 - Give IUPAC names for the following compounds:Ch. 20.1 - Draw structures corresponding to the following...Ch. 20.2 - Prob. 3P Ch. 20.2 - The Ka for dichloroacetic acid is 3.32 Ă— 10-2....Ch. 20.3 - Calculate the percentages of dissociated and...Ch. 20.4 - Which would you expect to be a stronger acid, the...Ch. 20.4 - Dicarboxylic acids have two dissociation...Ch. 20.4 - The pKa of p-cyclopropylbenzoic acid is 4.45. Is...Ch. 20.4 - Prob. 9P Ch. 20.5 - Prob. 10P

Solution Summary: The author explains that magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

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Chapter 20 Solutions