a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide Interpretation: Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity. Concept introduction: The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed. To arrange: Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Question

Indicate how the addition of a nucleophile :NuH2 to a ketone R-CO-R occurs.

Answer 1

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Indicate how the addition of a nucleophile :NuH2 to a ketone R-CO-R occurs.

Indicate the compound that gives us a primary carbocation and that gives us a secondary carbocation: R-CHO and R-CO-R

Draw a stepwise mechanism for the following reaction. OH

Answer 2

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 3

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 4

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 5

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 6

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Answer 7

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Answer 8

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Answer 9

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Answer 10

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 11

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 12

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Answer 23

Ch. 20.1 - Give IUPAC names for the following compounds:Ch. 20.1 - Draw structures corresponding to the following...Ch. 20.2 - Prob. 3P Ch. 20.2 - The Ka for dichloroacetic acid is 3.32 Ă— 10-2....Ch. 20.3 - Calculate the percentages of dissociated and...Ch. 20.4 - Which would you expect to be a stronger acid, the...Ch. 20.4 - Dicarboxylic acids have two dissociation...Ch. 20.4 - The pKa of p-cyclopropylbenzoic acid is 4.45. Is...Ch. 20.4 - Prob. 9P Ch. 20.5 - Prob. 10P

Solution Summary: The author explains that magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

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