Structural formula of the product for the alkene addition reaction has to be given. Concept Introduction: Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction. In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below, Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

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Answer 1

Question

Chapter 2, Problem 2.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 2, Problem 2.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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Answer 3

Question

Chapter 2, Problem 2.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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Answer 4

Question

Chapter 2, Problem 2.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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Answer 5

Chapter 2, Problem 2.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

Answer 6

Chapter 2, Problem 2.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

Answer 7

Chapter 2, Problem 2.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

Answer 14

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Answer 15

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Answer 17

Ch. 2.1 - Prob. 1QQ Ch. 2.1 - Prob. 2QQ Ch. 2.1 - Prob. 3QQ Ch. 2.2 - Prob. 1QQ Ch. 2.2 - Prob. 2QQ Ch. 2.2 - Prob. 3QQ Ch. 2.2 - Prob. 4QQ Ch. 2.3 - Prob. 1QQ Ch. 2.3 - Prob. 2QQ Ch. 2.3 - Prob. 3QQ

Solution Summary: The author explains the structure of the product for the alkene addition reaction.

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