Concept explainers
(a)
Interpretation:
The wrong thing if any is present in the given condensed structural formula of
Concept Introduction:
Hydrocarbons are the organic compounds that contain only hydrogen and carbon atoms. Hydrocarbon derivatives are the one in which the compounds contain hydrogen and carbon atoms along with one or more additional elements. The additional elements that can be present in hydrocarbon derivatives are oxygen, nitrogen, sulphur, chlorine, bromine etc.
Carbon has a total of four valence electrons. This means carbon can form four covalent bonds. Carbon atom is the main constituent in organic compounds. Carbon atom has the ability to form bonds with each other carbon atoms in a chain form, cyclic form or both. This is possible because of the electronic configuration of carbon atom. This is present in Group IVA of periodic table. Carbon has a total of four valence electrons. For the formation of any compounds, an additional four electrons are needed to give the carbon atom a octet configuration. Carbon can form covalent bonds like single, double and triple bond. Other bonds are not possible because, the octet configuration will be attained.
(b)
Interpretation:
The wrong thing if any is present in the given condensed structural formula of alkene has to be given.
Concept Introduction:
Hydrocarbons are the organic compounds that contain only hydrogen and carbon atoms. Hydrocarbon derivatives are the one in which the compounds contain hydrogen and carbon atoms along with one or more additional elements. The additional elements that can be present in hydrocarbon derivatives are oxygen, nitrogen, sulphur, chlorine, bromine etc.
Carbon has a total of four valence electrons. This means carbon can form four covalent bonds. Carbon atom is the main constituent in organic compounds. Carbon atom has the ability to form bonds with each other carbon atoms in a chain form, cyclic form or both. This is possible because of the electronic configuration of carbon atom. This is present in Group IVA of periodic table. Carbon has a total of four valence electrons. For the formation of any compounds, an additional four electrons are needed to give the carbon atom a octet configuration. Carbon can form covalent bonds like single, double and triple bond. Other bonds are not possible because, the octet configuration will be attained.

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Chapter 2 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
- TRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forwardRelative Transmittance 0.995 0.99 0.985 0.98 Please draw the structure that is consistent with all the spectral data below in the box and alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows. INFRARED SPECTRUM 1 0.975 3000 2000 Wavenumber (cm-1) 1000 Structure with assigned H peaks 1 3 180 160 140 120 100 f1 (ppm) 80 60 40 20 0 C-13 NMR note that there are 4 peaks between 120-140ppm Integral values equal the number of equivalent protons 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 fl (ppm)arrow_forwardCalculate the pH of 0.0025 M phenol.arrow_forward
- In the following reaction, the OH- acts as which of these? NO2-(aq) + H2O(l) ⇌ OH-(aq) + HNO2(aq)arrow_forwardUsing spectra attached, can the unknown be predicted? Draw the predicition. Please explain and provide steps. Molecular focrmula:C16H13ClOarrow_forwardCalculate the percent ionization for 0.0025 M phenol. Use the assumption to find [H3O+] first. K = 1.0 x 10-10arrow_forward
- The Ka for sodium dihydrogen phosphate is 6.32 x 10-8. Find the pH of a buffer made from 0.15 M H2PO4- and 0.25 M HPO42- .arrow_forwardThe Ka for lactic acid is 1.4 x 10-4. Find the pH of a buffer made from 0.066 M lactic acid and 0.088 M sodium lactate.arrow_forwardZaitsev's Rule 3) (a) Rank the following alkenes in order of decreasing stability. most stable A B C D > > > (b) Rank the following carbocations in order of decreasing stability least stable B C Darrow_forward
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