FOUND.OF COLLEGE CHEMISTRY
FOUND.OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781119234555
Author: Hein
Publisher: WILEY
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Chapter 19, Problem 41PE

(a)

Interpretation Introduction

Interpretation:

IUPAC names of given below alcohol has to be written and it should be classified as primary, secondary or tertiary.

    FOUND.OF COLLEGE CHEMISTRY             , Chapter 19, Problem 41PE , additional homework tip  1

Concept introduction:

IUAC gives rules for the naming of chemical compounds. These rules are,

Alcohol is the one of the type of organic compound with general structure of R-OH.

For saturated alcohols, longest chain with hydroxyl group is the parent chain of the compound and remaining groups and atoms are consider as substituent. In systematic name parent chain is ended with ol suffix.

In the nomenclature, Find the parent chin first then number the carbon atoms in the parent chain by giving lowest number to the hydroxyl substituted carbon followed by designate the other substituent in its position in parent chain.

If more than one same substituent or hydroxyl groups were occurs, add a prefix (di-, tri-, tetra-, ect..) in front of parent chain namsse.

Finally the systematic name was written as, the substituent position number with prefix (di-, tri-, tetra-, ect..) of number of substituents followed by name of the substituent then write the parent chain name (which contains large number of carbon atoms in the chain).

(b)

Interpretation Introduction

Interpretation:

IUPAC names of given below alcohol has to be written and it should be classified as primary, secondary or tertiary.

    FOUND.OF COLLEGE CHEMISTRY             , Chapter 19, Problem 41PE , additional homework tip  2

Concept introduction:

Refer part (a).

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1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.
(a) Enter the IUPAC name for this alcohol: CH,CH,CHCH, ОН Classify it as a primary, secondary, or tertiary alcohol: (b) Enter the IUPAC name for this alcohol: CH,CHCH,CH,CHOH CH, ČH, Classify it as a primary, secondary, or tertiary alcohol:
TRUE OR FALSE (a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions. (b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom. (c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups. (d) There are two alcohols with the molecular formula C3H8O. (e) There are three amines with the molecular formula C3H9N. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic…

Chapter 19 Solutions

FOUND.OF COLLEGE CHEMISTRY

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