The validation concerning the molecule, sphingosine according to the given description has to be stated. Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

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Answer 1

Question

Chapter 19, Problem 19.78EP

(a)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(b)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(c)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(d)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 19, Problem 19.78EP

(a)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(b)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(c)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(d)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

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Answer 3

Question

Chapter 19, Problem 19.78EP

(a)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(b)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(c)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(d)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Expert Solution & Answer

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Answer 4

Question

Chapter 19, Problem 19.78EP

(a)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(b)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(c)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(d)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Expert Solution & Answer

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Answer 5

Chapter 19, Problem 19.78EP

(a)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(b)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(c)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

(d)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 6

Chapter 19, Problem 19.78EP

(a)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 7

Chapter 19, Problem 19.78EP

(a)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 8

(b)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 9

(b)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 10

(c)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 11

(c)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 12

(d)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 13

(d)

Interpretation Introduction

Interpretation: The validation concerning the molecule, sphingosine according to the given description has to be stated.

Concept introduction: Sphingosine is the 18 carbon monounsaturated amino dialcohol platform for sphingolipids. Fatty acids and phosphate groups attached to sphingosine molecule and an alcohol attached to the phosphate group give sphingophospholipids.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19.1 - Prob. 1QQ Ch. 19.1 - Which of the following is not a biochemical...Ch. 19.1 - The saponifiable/nonsaponifiable classification...Ch. 19.2 - Prob. 1QQ Ch. 19.2 - Prob. 2QQ Ch. 19.2 - Prob. 3QQ Ch. 19.2 - Prob. 4QQ Ch. 19.3 - Prob. 1QQ Ch. 19.3 - Prob. 2QQ Ch. 19.4 - How many structural subunits are present in the...

Solution Summary: The author explains that the validation concerning the molecule, sphingosine according to the given description has to be stated.

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