
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 19.6, Problem 6QQ
Interpretation Introduction
Interpretation: In the oxidation of fats and oils, the structural part which attacked by the oxidizing agent has to be predicted.
Concept introduction: During oxidation of a triacylglycerol, the carbon-carbon double bonds break down to form an
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3. Predict the major product and give a mechanism for the following reactions:
(CH3)3COH/H₂SO4
a)
b)
NC
CH₂O
c)
LOCH,
(CH3)3COH/H2SO4
H,SO
-OH
Indicate if the aldehyde shown reacts with the provided nucleophiles in acid or base
conditions.
a NaBH4
be Li
eli
-NH2
P(Ph3)
f
KCN
g
OH excess
h CH3OH
i NaCHCCH3
Predict the major products of the following organic reaction:
+
A
?
Some important notes:
• Draw the major product, or products, of the reaction in the drawing area below.
• If there aren't any products, because no reaction will take place, check the box below the drawing area instead.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are
enantiomers.
Explanation
Check
Click and drag to start drawing a structure.
C
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Chapter 19 Solutions
General, Organic, and Biological Chemistry
Ch. 19.1 - Prob. 1QQCh. 19.1 - Which of the following is not a biochemical...Ch. 19.1 - The saponifiable/nonsaponifiable classification...Ch. 19.2 - Prob. 1QQCh. 19.2 - Prob. 2QQCh. 19.2 - Prob. 3QQCh. 19.2 - Prob. 4QQCh. 19.3 - Prob. 1QQCh. 19.3 - Prob. 2QQCh. 19.4 - How many structural subunits are present in the...
Ch. 19.4 - Prob. 2QQCh. 19.4 - How many different simple triglyceride molecules...Ch. 19.4 - Prob. 4QQCh. 19.4 - Prob. 5QQCh. 19.4 - Unsaturated fatty acid residues are structural...Ch. 19.5 - Prob. 1QQCh. 19.5 - Prob. 2QQCh. 19.5 - Prob. 3QQCh. 19.6 - Prob. 1QQCh. 19.6 - Prob. 2QQCh. 19.6 - Prob. 3QQCh. 19.6 - Prob. 4QQCh. 19.6 - Prob. 5QQCh. 19.6 - Prob. 6QQCh. 19.7 - Based on biological function, phospholipids are...Ch. 19.7 - Prob. 2QQCh. 19.7 - Which of the following statements about the...Ch. 19.7 - When the head and two tails structural model is...Ch. 19.7 - Prob. 5QQCh. 19.7 - Prob. 6QQCh. 19.8 - The number of structural building blocks present...Ch. 19.8 - Prob. 2QQCh. 19.9 - Prob. 1QQCh. 19.9 - Which of the following types of membrane lipids...Ch. 19.9 - Prob. 3QQCh. 19.10 - Which of the following is a correct representation...Ch. 19.10 - Prob. 2QQCh. 19.10 - Prob. 3QQCh. 19.10 - Prob. 4QQCh. 19.10 - Which of the following membrane transport...Ch. 19.11 - Which of the following statements concerning bile...Ch. 19.11 - Which of the following statements concerning...Ch. 19.12 - Prob. 1QQCh. 19.12 - Prob. 2QQCh. 19.12 - Prob. 3QQCh. 19.13 - Prob. 1QQCh. 19.13 - Aspirin reduces inflammation and fever by...Ch. 19.13 - Prob. 3QQCh. 19.14 - Prob. 1QQCh. 19.14 - Prob. 2QQCh. 19.14 - Prob. 3QQCh. 19.15 - In which of the following pairs of lipid types are...Ch. 19.15 - Prob. 2QQCh. 19.15 - Prob. 3QQCh. 19 - Indicate whether each of the following general...Ch. 19 - Indicate whether each of the following general...Ch. 19 - Would you expect lipids to be soluble or insoluble...Ch. 19 - Would you expect lipids to be soluble or insoluble...Ch. 19 - What is the biochemical function category for each...Ch. 19 - What is the biochemical function category for each...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Prob. 19.11EPCh. 19 - Prob. 19.12EPCh. 19 - Prob. 19.13EPCh. 19 - Prob. 19.14EPCh. 19 - Prob. 19.15EPCh. 19 - Classify each of the fatty acids in Problem 19-14...Ch. 19 - Draw the condensed structural formula for the...Ch. 19 - Draw the condensed structural formula for the...Ch. 19 - Prob. 19.19EPCh. 19 - Using the information given in Table 19-1, assign...Ch. 19 - What is the relationship between carbon chain...Ch. 19 - What is the relationship between degree of...Ch. 19 - What structural change is associated with the...Ch. 19 - Why does the introduction of a cis-double bond...Ch. 19 - In each of the following pairs of fatty acids,...Ch. 19 - In each of the following pairs of fatty acids,...Ch. 19 - What are the four structural subunits that...Ch. 19 - Draw the general block diagram for a...Ch. 19 - Prob. 19.29EPCh. 19 - Prob. 19.30EPCh. 19 - Draw the condensed structural formula of a...Ch. 19 - Draw the condensed structural formula of a...Ch. 19 - Draw block diagram structures for the four...Ch. 19 - Draw block diagram structures for the three...Ch. 19 - Identify, by common name, fatty acids present in...Ch. 19 - Identify, by common name, fatty acids present in...Ch. 19 - Prob. 19.37EPCh. 19 - Prob. 19.38EPCh. 19 - Prob. 19.39EPCh. 19 - Prob. 19.40EPCh. 19 - Prob. 19.41EPCh. 19 - Prob. 19.42EPCh. 19 - Prob. 19.43EPCh. 19 - Prob. 19.44EPCh. 19 - Prob. 19.45EPCh. 19 - Prob. 19.46EPCh. 19 - For each of the triacylglycerol molecules in...Ch. 19 - For each of the triacylglycerol molecules in...Ch. 19 - What are the general names for the products...Ch. 19 - What additional products are formed when a...Ch. 19 - Classify each of the reaction situations in...Ch. 19 - Prob. 19.52EPCh. 19 - Draw condensed structural formulas for all...Ch. 19 - Draw condensed structural formulas for all...Ch. 19 - Prob. 19.55EPCh. 19 - Draw condensed structural formulas for all...Ch. 19 - Why can only unsaturated triacylglycerols undergo...Ch. 19 - Prob. 19.58EPCh. 19 - How many molecules of H2 will react with one...Ch. 19 - How many molecules of H2 will react with one...Ch. 19 - Prob. 19.61EPCh. 19 - Prob. 19.62EPCh. 19 - Prob. 19.63EPCh. 19 - Prob. 19.64EPCh. 19 - Prob. 19.65EPCh. 19 - Prob. 19.66EPCh. 19 - Prob. 19.67EPCh. 19 - Prob. 19.68EPCh. 19 - The following is a block diagram for a...Ch. 19 - Prob. 19.70EPCh. 19 - Prob. 19.71EPCh. 19 - Prob. 19.72EPCh. 19 - Prob. 19.73EPCh. 19 - Indicate whether each of the following statements...Ch. 19 - Based on the head and two tails model for the...Ch. 19 - Based on the head and two tails model for the...Ch. 19 - Prob. 19.77EPCh. 19 - Prob. 19.78EPCh. 19 - Prob. 19.79EPCh. 19 - Prob. 19.80EPCh. 19 - Prob. 19.81EPCh. 19 - Prob. 19.82EPCh. 19 - Prob. 19.83EPCh. 19 - Prob. 19.84EPCh. 19 - Which of the terms triacylglycerol,...Ch. 19 - Prob. 19.86EPCh. 19 - Prob. 19.87EPCh. 19 - Which of the terms triacylglycerol,...Ch. 19 - Prob. 19.89EPCh. 19 - Prob. 19.90EPCh. 19 - Prob. 19.91EPCh. 19 - Prob. 19.92EPCh. 19 - Prob. 19.93EPCh. 19 - Prob. 19.94EPCh. 19 - Prob. 19.95EPCh. 19 - Prob. 19.96EPCh. 19 - Give numerical answers to the following questions...Ch. 19 - Prob. 19.98EPCh. 19 - Prob. 19.99EPCh. 19 - Prob. 19.100EPCh. 19 - In a dietary context, what is the difference...Ch. 19 - Prob. 19.102EPCh. 19 - Prob. 19.103EPCh. 19 - Prob. 19.104EPCh. 19 - Indicate whether each of the following statements...Ch. 19 - Indicate whether each of the following statements...Ch. 19 - What is the function of unsaturation in the...Ch. 19 - Prob. 19.108EPCh. 19 - Prob. 19.109EPCh. 19 - Prob. 19.110EPCh. 19 - Prob. 19.111EPCh. 19 - Prob. 19.112EPCh. 19 - Prob. 19.113EPCh. 19 - Prob. 19.114EPCh. 19 - Prob. 19.115EPCh. 19 - Prob. 19.116EPCh. 19 - Prob. 19.117EPCh. 19 - Prob. 19.118EPCh. 19 - Prob. 19.119EPCh. 19 - Prob. 19.120EPCh. 19 - Prob. 19.121EPCh. 19 - Prob. 19.122EPCh. 19 - Prob. 19.123EPCh. 19 - Prob. 19.124EPCh. 19 - What is the medium through which bile acids are...Ch. 19 - What is the chemical composition of bile?Ch. 19 - At what location in the body are bile acids stored...Ch. 19 - Prob. 19.128EPCh. 19 - Prob. 19.129EPCh. 19 - Prob. 19.130EPCh. 19 - Prob. 19.131EPCh. 19 - Prob. 19.132EPCh. 19 - Prob. 19.133EPCh. 19 - Prob. 19.134EPCh. 19 - Prob. 19.135EPCh. 19 - Prob. 19.136EPCh. 19 - Prob. 19.137EPCh. 19 - Prob. 19.138EPCh. 19 - Draw the structure of an anabolic steroid with the...Ch. 19 - Prob. 19.140EPCh. 19 - What is the major structural difference between a...Ch. 19 - What is the major structural difference between a...Ch. 19 - Prob. 19.143EPCh. 19 - What structural feature distinguishes a...Ch. 19 - Classify each of the following types of lipids as...Ch. 19 - Classify each of the following types of lipids as...Ch. 19 - Prob. 19.147EPCh. 19 - Prob. 19.148EPCh. 19 - Prob. 19.149EPCh. 19 - Draw the condensed structural formula of a wax...Ch. 19 - Prob. 19.151EPCh. 19 - Biological waxes have a head and two tails...Ch. 19 - Which of the substance categories biological wax,...Ch. 19 - Which of the substance categories biological wax,...Ch. 19 - Prob. 19.155EPCh. 19 - Prob. 19.156EPCh. 19 - Prob. 19.157EPCh. 19 - Indicate whether or not each of the following...Ch. 19 - Prob. 19.159EPCh. 19 - Prob. 19.160EPCh. 19 - Prob. 19.161EPCh. 19 - Prob. 19.162EP
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