
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Chapter 19, Problem 19.149EP
Interpretation Introduction
Interpretation: The general block diagram for a biological wax has to be drawn.
Concept introduction: Biological wax is a type of protective-coating lipid. It is insoluble in water. It is a water repellent lipid with protective-coating and lubricant functions.
Expert Solution & Answer

Trending nowThis is a popular solution!

Students have asked these similar questions
An unknown weak acid with a concentration of 0.410 M has a pH of 5.600. What is the Ka of the weak acid?
(racemic)
19.84 Using your reaction roadmaps as a guide, show how to convert 2-oxepanone and ethanol
into 1-cyclopentenecarbaldehyde. You must use 2-oxepanone as the source of all carbon
atoms in the target molecule. Show all reagents and all molecules synthesized along
the way.
&
+ EtOH
H
2-Oxepanone
1-Cyclopentenecarbaldehyde
R₂
R₁
R₁
a
R
Rg
Nu
R₂
Rg
R₁
R
R₁₂
R3
R
R
Nu enolate forming
R₁ R
B-Alkylated carbonyl
species or amines
Cyclic B-Ketoester
R₁₁
HOB
R
R₁B
R
R₁₂
B-Hydroxy carbonyl
R
diester
R2 R3
R₁
RB
OR
R₂ 0
aB-Unsaturated carbonyl
NaOR
Aldol
HOR
reaction
1) LDA
2) R-X
3) H₂O/H₂O
ketone,
aldehyde
1) 2°-amine
2) acid chloride
3) H₂O'/H₂O
0
O
R₁
R₁
R
R₁
R₁₂
Alkylated a-carbon
R₁
H.C
R₁
H.C
Alkylated methyl ketone
acetoacetic
ester
B-Ketoester
ester
R₁
HO
R₂ R
B-Dicarbonyl
HO
Alkylated carboxylic acid
malonic ester
Write the reagents required to bring about each reaction next to the arrows shown.
Next, record any regiochemistry or stereochemistry considerations relevant to the
reaction. You should also record any key aspects of the mechanism, such as forma-
tion of an important intermediate, as a helpful reminder. You may want to keep
track of all reactions that make carbon-carbon bonds, because these help you build
large molecules from smaller fragments. This especially applies to the reactions in…
Chapter 19 Solutions
General, Organic, and Biological Chemistry
Ch. 19.1 - Prob. 1QQCh. 19.1 - Which of the following is not a biochemical...Ch. 19.1 - The saponifiable/nonsaponifiable classification...Ch. 19.2 - Prob. 1QQCh. 19.2 - Prob. 2QQCh. 19.2 - Prob. 3QQCh. 19.2 - Prob. 4QQCh. 19.3 - Prob. 1QQCh. 19.3 - Prob. 2QQCh. 19.4 - How many structural subunits are present in the...
Ch. 19.4 - Prob. 2QQCh. 19.4 - How many different simple triglyceride molecules...Ch. 19.4 - Prob. 4QQCh. 19.4 - Prob. 5QQCh. 19.4 - Unsaturated fatty acid residues are structural...Ch. 19.5 - Prob. 1QQCh. 19.5 - Prob. 2QQCh. 19.5 - Prob. 3QQCh. 19.6 - Prob. 1QQCh. 19.6 - Prob. 2QQCh. 19.6 - Prob. 3QQCh. 19.6 - Prob. 4QQCh. 19.6 - Prob. 5QQCh. 19.6 - Prob. 6QQCh. 19.7 - Based on biological function, phospholipids are...Ch. 19.7 - Prob. 2QQCh. 19.7 - Which of the following statements about the...Ch. 19.7 - When the head and two tails structural model is...Ch. 19.7 - Prob. 5QQCh. 19.7 - Prob. 6QQCh. 19.8 - The number of structural building blocks present...Ch. 19.8 - Prob. 2QQCh. 19.9 - Prob. 1QQCh. 19.9 - Which of the following types of membrane lipids...Ch. 19.9 - Prob. 3QQCh. 19.10 - Which of the following is a correct representation...Ch. 19.10 - Prob. 2QQCh. 19.10 - Prob. 3QQCh. 19.10 - Prob. 4QQCh. 19.10 - Which of the following membrane transport...Ch. 19.11 - Which of the following statements concerning bile...Ch. 19.11 - Which of the following statements concerning...Ch. 19.12 - Prob. 1QQCh. 19.12 - Prob. 2QQCh. 19.12 - Prob. 3QQCh. 19.13 - Prob. 1QQCh. 19.13 - Aspirin reduces inflammation and fever by...Ch. 19.13 - Prob. 3QQCh. 19.14 - Prob. 1QQCh. 19.14 - Prob. 2QQCh. 19.14 - Prob. 3QQCh. 19.15 - In which of the following pairs of lipid types are...Ch. 19.15 - Prob. 2QQCh. 19.15 - Prob. 3QQCh. 19 - Indicate whether each of the following general...Ch. 19 - Indicate whether each of the following general...Ch. 19 - Would you expect lipids to be soluble or insoluble...Ch. 19 - Would you expect lipids to be soluble or insoluble...Ch. 19 - What is the biochemical function category for each...Ch. 19 - What is the biochemical function category for each...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Classify each of the following fatty acids as...Ch. 19 - Prob. 19.11EPCh. 19 - Prob. 19.12EPCh. 19 - Prob. 19.13EPCh. 19 - Prob. 19.14EPCh. 19 - Prob. 19.15EPCh. 19 - Classify each of the fatty acids in Problem 19-14...Ch. 19 - Draw the condensed structural formula for the...Ch. 19 - Draw the condensed structural formula for the...Ch. 19 - Prob. 19.19EPCh. 19 - Using the information given in Table 19-1, assign...Ch. 19 - What is the relationship between carbon chain...Ch. 19 - What is the relationship between degree of...Ch. 19 - What structural change is associated with the...Ch. 19 - Why does the introduction of a cis-double bond...Ch. 19 - In each of the following pairs of fatty acids,...Ch. 19 - In each of the following pairs of fatty acids,...Ch. 19 - What are the four structural subunits that...Ch. 19 - Draw the general block diagram for a...Ch. 19 - Prob. 19.29EPCh. 19 - Prob. 19.30EPCh. 19 - Draw the condensed structural formula of a...Ch. 19 - Draw the condensed structural formula of a...Ch. 19 - Draw block diagram structures for the four...Ch. 19 - Draw block diagram structures for the three...Ch. 19 - Identify, by common name, fatty acids present in...Ch. 19 - Identify, by common name, fatty acids present in...Ch. 19 - Prob. 19.37EPCh. 19 - Prob. 19.38EPCh. 19 - Prob. 19.39EPCh. 19 - Prob. 19.40EPCh. 19 - Prob. 19.41EPCh. 19 - Prob. 19.42EPCh. 19 - Prob. 19.43EPCh. 19 - Prob. 19.44EPCh. 19 - Prob. 19.45EPCh. 19 - Prob. 19.46EPCh. 19 - For each of the triacylglycerol molecules in...Ch. 19 - For each of the triacylglycerol molecules in...Ch. 19 - What are the general names for the products...Ch. 19 - What additional products are formed when a...Ch. 19 - Classify each of the reaction situations in...Ch. 19 - Prob. 19.52EPCh. 19 - Draw condensed structural formulas for all...Ch. 19 - Draw condensed structural formulas for all...Ch. 19 - Prob. 19.55EPCh. 19 - Draw condensed structural formulas for all...Ch. 19 - Why can only unsaturated triacylglycerols undergo...Ch. 19 - Prob. 19.58EPCh. 19 - How many molecules of H2 will react with one...Ch. 19 - How many molecules of H2 will react with one...Ch. 19 - Prob. 19.61EPCh. 19 - Prob. 19.62EPCh. 19 - Prob. 19.63EPCh. 19 - Prob. 19.64EPCh. 19 - Prob. 19.65EPCh. 19 - Prob. 19.66EPCh. 19 - Prob. 19.67EPCh. 19 - Prob. 19.68EPCh. 19 - The following is a block diagram for a...Ch. 19 - Prob. 19.70EPCh. 19 - Prob. 19.71EPCh. 19 - Prob. 19.72EPCh. 19 - Prob. 19.73EPCh. 19 - Indicate whether each of the following statements...Ch. 19 - Based on the head and two tails model for the...Ch. 19 - Based on the head and two tails model for the...Ch. 19 - Prob. 19.77EPCh. 19 - Prob. 19.78EPCh. 19 - Prob. 19.79EPCh. 19 - Prob. 19.80EPCh. 19 - Prob. 19.81EPCh. 19 - Prob. 19.82EPCh. 19 - Prob. 19.83EPCh. 19 - Prob. 19.84EPCh. 19 - Which of the terms triacylglycerol,...Ch. 19 - Prob. 19.86EPCh. 19 - Prob. 19.87EPCh. 19 - Which of the terms triacylglycerol,...Ch. 19 - Prob. 19.89EPCh. 19 - Prob. 19.90EPCh. 19 - Prob. 19.91EPCh. 19 - Prob. 19.92EPCh. 19 - Prob. 19.93EPCh. 19 - Prob. 19.94EPCh. 19 - Prob. 19.95EPCh. 19 - Prob. 19.96EPCh. 19 - Give numerical answers to the following questions...Ch. 19 - Prob. 19.98EPCh. 19 - Prob. 19.99EPCh. 19 - Prob. 19.100EPCh. 19 - In a dietary context, what is the difference...Ch. 19 - Prob. 19.102EPCh. 19 - Prob. 19.103EPCh. 19 - Prob. 19.104EPCh. 19 - Indicate whether each of the following statements...Ch. 19 - Indicate whether each of the following statements...Ch. 19 - What is the function of unsaturation in the...Ch. 19 - Prob. 19.108EPCh. 19 - Prob. 19.109EPCh. 19 - Prob. 19.110EPCh. 19 - Prob. 19.111EPCh. 19 - Prob. 19.112EPCh. 19 - Prob. 19.113EPCh. 19 - Prob. 19.114EPCh. 19 - Prob. 19.115EPCh. 19 - Prob. 19.116EPCh. 19 - Prob. 19.117EPCh. 19 - Prob. 19.118EPCh. 19 - Prob. 19.119EPCh. 19 - Prob. 19.120EPCh. 19 - Prob. 19.121EPCh. 19 - Prob. 19.122EPCh. 19 - Prob. 19.123EPCh. 19 - Prob. 19.124EPCh. 19 - What is the medium through which bile acids are...Ch. 19 - What is the chemical composition of bile?Ch. 19 - At what location in the body are bile acids stored...Ch. 19 - Prob. 19.128EPCh. 19 - Prob. 19.129EPCh. 19 - Prob. 19.130EPCh. 19 - Prob. 19.131EPCh. 19 - Prob. 19.132EPCh. 19 - Prob. 19.133EPCh. 19 - Prob. 19.134EPCh. 19 - Prob. 19.135EPCh. 19 - Prob. 19.136EPCh. 19 - Prob. 19.137EPCh. 19 - Prob. 19.138EPCh. 19 - Draw the structure of an anabolic steroid with the...Ch. 19 - Prob. 19.140EPCh. 19 - What is the major structural difference between a...Ch. 19 - What is the major structural difference between a...Ch. 19 - Prob. 19.143EPCh. 19 - What structural feature distinguishes a...Ch. 19 - Classify each of the following types of lipids as...Ch. 19 - Classify each of the following types of lipids as...Ch. 19 - Prob. 19.147EPCh. 19 - Prob. 19.148EPCh. 19 - Prob. 19.149EPCh. 19 - Draw the condensed structural formula of a wax...Ch. 19 - Prob. 19.151EPCh. 19 - Biological waxes have a head and two tails...Ch. 19 - Which of the substance categories biological wax,...Ch. 19 - Which of the substance categories biological wax,...Ch. 19 - Prob. 19.155EPCh. 19 - Prob. 19.156EPCh. 19 - Prob. 19.157EPCh. 19 - Indicate whether or not each of the following...Ch. 19 - Prob. 19.159EPCh. 19 - Prob. 19.160EPCh. 19 - Prob. 19.161EPCh. 19 - Prob. 19.162EP
Knowledge Booster
Similar questions
- When anisole is treated with excess bromine, the reaction gives a product which shows two singlets in 1H NMR. Draw the product.arrow_forward(ii) Draw a reasonable mechanism for the following reaction: CI NaOH heat OH (hint: SNAr Reaction) :arrow_forwardDraw the major product in each of the following reaction:arrow_forward
- Draw the mechanism for the following Friedel-Craft reaction. AlBr3 Brarrow_forward(a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Consider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- World of ChemistryChemistryISBN:9780618562763Author:Steven S. ZumdahlPublisher:Houghton Mifflin College DivChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning

General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning

Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,

Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning

World of Chemistry
Chemistry
ISBN:9780618562763
Author:Steven S. Zumdahl
Publisher:Houghton Mifflin College Div

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning