The reaction involved in the production of chlorine dioxide ( ClO 2 ) is given. The value of E ° and Δ G ° for the given chemical reaction is to be calculated. Concept introduction: The species with higher reduction potential undergoes reduction at the cathode while the species with lower reduction potential undergoes oxidation at the anode. The change in Gibbs free energy is the useful amount work that can be done and negative value of Δ G ° shows that the reaction is spontaneous in nature. To determine: The value of E ° and Δ G ° for the given reaction.

Question

Want to see the full answer?

Answer 1

Question

Chapter 17, Problem 49E

Interpretation Introduction

Interpretation:

The reaction involved in the production of chlorine dioxide (ClO2) is given. The value of E° and ΔG° for the given chemical reaction is to be calculated.

Concept introduction:

The species with higher reduction potential undergoes reduction at the cathode while the species with lower reduction potential undergoes oxidation at the anode. The change in Gibbs free energy is the useful amount work that can be done and negative value of ΔG° shows that the reaction is spontaneous in nature.

To determine: The value of E° and ΔG° for the given reaction.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…