Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 17, Problem 17.64E
Interpretation Introduction
Interpretation:
The reason corresponding to the fact that drink can contain aspartame as a sweetener and yet be low in calories is to be explained.
Concept introduction:
Aspartame is an artificial sweetening agent which can be used as a substitute for the sucrose or the regular sugar. Unlike sugars, it is a non-saccharide compound and it is the methyl ester of aspartic acid.
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 17 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 17 - Prob. 17.1ECh. 17 - Describe whether each of the following substances...Ch. 17 - Prob. 17.3ECh. 17 - Prob. 17.4ECh. 17 - Prob. 17.5ECh. 17 - Why are carbon atoms 1 and 3 of glyceraldehyde not...Ch. 17 - Prob. 17.7ECh. 17 - Which of the following molecules can have...Ch. 17 - Which of the following molecules can have...Ch. 17 - Prob. 17.10E
Ch. 17 - Prob. 17.11ECh. 17 - Prob. 17.12ECh. 17 - Prob. 17.13ECh. 17 - Draw Fischer projections for both the D and L...Ch. 17 - Prob. 17.15ECh. 17 - Prob. 17.16ECh. 17 - Prob. 17.17ECh. 17 - Prob. 17.18ECh. 17 - Prob. 17.19ECh. 17 - Prob. 17.20ECh. 17 - Prob. 17.21ECh. 17 - Prob. 17.22ECh. 17 - Prob. 17.23ECh. 17 - Prob. 17.24ECh. 17 - Prob. 17.25ECh. 17 - Prob. 17.26ECh. 17 - Prob. 17.27ECh. 17 - Prob. 17.28ECh. 17 - Prob. 17.29ECh. 17 - Prob. 17.30ECh. 17 - Prob. 17.31ECh. 17 - Prob. 17.32ECh. 17 - Prob. 17.33ECh. 17 - Prob. 17.34ECh. 17 - Prob. 17.35ECh. 17 - Prob. 17.36ECh. 17 - Prob. 17.37ECh. 17 - Prob. 17.38ECh. 17 - Prob. 17.39ECh. 17 - Prob. 17.40ECh. 17 - Prob. 17.41ECh. 17 - Prob. 17.42ECh. 17 - Prob. 17.43ECh. 17 - Prob. 17.44ECh. 17 - Prob. 17.45ECh. 17 - Prob. 17.46ECh. 17 - Prob. 17.47ECh. 17 - Sucrose and honey are commonly used sweeteners....Ch. 17 - Prob. 17.49ECh. 17 - Prob. 17.50ECh. 17 - Prob. 17.51ECh. 17 - Prob. 17.52ECh. 17 - Prob. 17.53ECh. 17 - Prob. 17.54ECh. 17 - Prob. 17.55ECh. 17 - Prob. 17.56ECh. 17 - Prob. 17.57ECh. 17 - Prob. 17.58ECh. 17 - Prob. 17.59ECh. 17 - Prob. 17.60ECh. 17 - Prob. 17.61ECh. 17 - Prob. 17.62ECh. 17 - Prob. 17.63ECh. 17 - Prob. 17.64ECh. 17 - Prob. 17.65ECh. 17 - Prob. 17.66ECh. 17 - Prob. 17.67ECh. 17 - Prob. 17.68ECh. 17 - Prob. 17.69ECh. 17 - Prob. 17.70ECh. 17 - Prob. 17.71ECh. 17 - Prob. 17.72ECh. 17 - Prob. 17.73ECh. 17 - Glucose is a reducing sugar, which if boiled in...Ch. 17 - Prob. 17.75E
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- Assign this H NMRarrow_forwardPlease complete these blanks need that asaparrow_forwardNitration of Methyl Benzoate: 1. Predict the major product for the reaction below AND provide a mechanism. Include ALL resonance structures for the intermediate. C(CH3)3 NO₂* ? 2. Assuming the stoichiometry is 1:1 for the reaction above, what volume of concentrated nitric acid would be required to mononitrate 0.50 grams of the compound above? What product(s) might you expect if you nitrated phenol instead of methyl benzoate? Explain your reasoning. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
- Sodium Borohydride Reduction (continued on the next page): 1. Draw the product of each of the reactions below and give the formula mass to the nearest whole number. ? (1) NaBH (2) acid (1) NaBD4 (2) acid ? 2. In mass spectra, alcohols typically break as shown in equation 8 in chapter 11 (refer to your lab manual). The larger group is generally lost and this gives rise to the base peak in the mass spectrum. For the products of each of the reactions in question # 1, draw the ion corresponding to the base peak for that product and give its mass to charge ratio (m/z). 3. Given the reaction below, calculate how many mg of 1-phenyl-1-butanol that can be produced using 31 mg NaBH4 and an excess of butyrophenone. 4. + NaBH4 OH (after workup with dilute HCI) What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAspirin from Wintergreen: 1. In isolating the salicylic acid, why is it important to press out as much of the water as possible? Write a step-by-step mechanism for the esterification of salicylic acid with acetic anhydride catalyzed by concentrated H₂SO4. 3. Calculate the exact monoisotopic mass of aspirin showing your work. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSynthesis of Ibuprofen-Part 1: 1. What characteristic absorption band changes would you expect in the IR spectrum on going from p-isobutylacetophenone to 1-(4-isobutylphenyl)-ethanol and then to 1-(4-isobutylphenyl)-1-choroethane as you did in the experiment today? Give approximate wavenumbers associated with each functional group change. Given that the mechanism of the chlorination reaction today involves formation of a benzylic carbocation, explain why the following rearranged product is not formed. محرم محمد 3. Why do we use dilute HCl for the first step of the reaction today and concentrated HCI for the second step? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
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