To write the product for the given reaction. Concept introduction: When a ketone reacts with a diol , the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Determine the major product of the following reaction OH H3O* H2 Pd

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 5

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 6

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 7

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.2 - Prob. 4P Ch. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9P Ch. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P

Solution Summary: The author explains how ketone reacts with a diol, and the reaction is used to protect aldehydes and ketones.

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Chapter 16 Solutions