Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction Concept introduction: Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an S N 2 reaction. For example, the structure of 2-methyl propane 2-thiol.

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Answer 1

Question

Chapter 16, Problem 64P

a.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

b.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. What will be formed if the alkyl halide employed is pentyl bromide.

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

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What products are obtained from the reaction of the following compounds with LiAlH4 followed by treatment with dilute acid? a. ethyl butanoate c. methyl benzoate b. benzoic acid d. pentanoic acid

Thiols can be prepared from the reaction of thiourea with an alkyl halide, followed by hydroxide-ion-promoted hydrolysis. a. Propose a mechanism for the reaction. b. What thiol will be formed if the alkyl halide employed is pentyl bromide?

Acetals are often prepared during the synthetic sequence to protect the carbonyl group of an aldehyde or ketone. Such an acetal is not reactive to each of the following reagents except: a.) LiAlH4 b.) PCC(Collins) c.) H3O+ d.) RMgBr e.) NaOH

Answer 2

Question

Chapter 16, Problem 64P

a.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

b.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. What will be formed if the alkyl halide employed is pentyl bromide.

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Expert Solution & Answer

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Answer 3

Question

Chapter 16, Problem 64P

a.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

b.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. What will be formed if the alkyl halide employed is pentyl bromide.

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Chapter 16, Problem 64P

a.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

b.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. What will be formed if the alkyl halide employed is pentyl bromide.

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 64P

a.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

b.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. What will be formed if the alkyl halide employed is pentyl bromide.

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Answer 6

Chapter 16, Problem 64P

a.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Answer 7

Chapter 16, Problem 64P

a.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. Propose a mechanism for the reaction

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Answer 8

b.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. What will be formed if the alkyl halide employed is pentyl bromide.

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Answer 9

b.

Interpretation Introduction

Interpretation:

Thiols can be prepared from the reaction of thiourea with an alkyl halide , followed by hydroxide –io-promoted hydrolysis. What will be formed if the alkyl halide employed is pentyl bromide.

Concept introduction:

Organosulfur compound that contains a carbon –bonded sulfhydry group are called thiols. It has strong odour. The –SH froup is called a mercapto group. Named by adding the suffix –thiol to the alkane name. They are commonly prepared by an SN2 reaction.

For example, the structure of 2-methyl propane 2-thiol.

Answer 10

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Answer 13

Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.2 - Prob. 4P Ch. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9P Ch. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P

Solution Summary: The author explains how thiols can be prepared from a reaction with an alkyl halide, followed by hydroxide –io-promoted hydrolysis.

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