the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

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Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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When the rate constants for the hydrolysis of several morpholine enamines of para-substituted propiophenones are determined at pH 4.7, the r value is positive; however, when the rates of hydrolysis are determined at pH 10.4, the r value is negative. a. What is the rate-determining step of the hydrolysis reaction when it is carried out in a basic solution? b. What is the rate-determining step of the hydrolysis reaction when it is carried out in an acidic solution?

Which of the following reactions would produce an enamine as the major product? Assume that there are means to remove water from the reaction. A a b C C D d E e HN product NaCN, acetone H. A pH 4-5 D product H CH;NH2 product H2N– NH2 рH 4-5 → product H pH 4-5 HN. + product pH 4-5 B.

In the reaction of a nitrile with a Grignard reagent, there are two steps: a) nucleophilic addition of the Grignard to form an imine ion and b) hydrolysis of the imine to form a ketone. Draw the intermediate and the final product in this reaction. Ignore inorganic byproducts. 1. CH₂MgBr 2. H3O* Draw Imine Ion Intermediate 1. H30¹ 2. Neutralizing work-up a

Answer 2

Question

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Answer 3

Question

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Answer 4

Question

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Answer 5

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

Answer 6

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Answer 7

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

Answer 10

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Answer 11

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Answer 13

Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.2 - Prob. 4P Ch. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9P Ch. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Solution Summary: The author describes the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

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the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Chapter 16 Solutions

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Solution Summary: The author describes the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Concept explainers

Videos

Interpretation: the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Interpretation: The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Chapter 16 Solutions

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.