The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified. Concept introduction: Wittig reaction: Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene . Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods. Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene. The mechanism of the witting reaction is:

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Answer 1

Question

Chapter 16, Problem 89P

(a)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(b)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(c)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(d)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

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Consider this step in a radical reaction: Br N O hv What type of step is this? Check all that apply. Draw the products of the step on the right-hand side of the drawing area below. If more than one set of products is possible, draw any set. Also, draw the mechanism arrows on the left-hand side of the drawing area to show how this happens. O primary Otermination O initialization O electrophilic O none of the above × ☑

None

Can I get a drawing of what is happening with the orbitals (particularly the p orbital) on the O in the OH group? Is the p orbital on the O involved in the ring resonance? Why or why not?

Answer 2

Question

Chapter 16, Problem 89P

(a)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(b)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(c)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(d)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

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Answer 3

Question

Chapter 16, Problem 89P

(a)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(b)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(c)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(d)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

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Answer 4

Question

Chapter 16, Problem 89P

(a)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(b)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(c)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(d)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

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Answer 5

Chapter 16, Problem 89P

(a)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(b)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(c)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

(d)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 6

Chapter 16, Problem 89P

(a)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 7

Chapter 16, Problem 89P

(a)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 8

(b)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 9

(b)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 10

(c)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 11

(c)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 12

(d)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 13

(d)

Interpretation Introduction

Interpretation:

The carbonyl carbon and phosphonium ylide that are needed to synthesize the given compound has to be identified.

Concept introduction:

Wittig reaction:

Witting reaction is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium ylide to give an alkene. Wittig reaction is a very useful method to synthesize the compound which can’t be synthesis easily by other methods.

Specific phosphonium ylide can be prepared for specific alkene synthesis. The triphenylphosphine is reacted with alkyl halide that has required numbers of carbon. A strong base such as sodium hydride or butyllithium is added to remove proton of carbon adjacent to the phosphorus atom. The carbon of prepared phosphonium ylide have nucleophilic character and get attached to the carbonyl carbon and carbonyl oxygen get attached to the positively charged phosphorous. Triphenylphosphine oxide gets eliminated resulting in the formation of the alkene.

The mechanism of the witting reaction is:

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.2 - Prob. 4P Ch. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9P Ch. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P

Solution Summary: The author explains the mechanism of the witting reaction, which is the reaction between the carbonyl carbon of aldehyde or ketone and the phosphonium

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