(a)
Interpretation:
It should be determined that the product obtained from the reaction of Ethyl butanoate with
Concept introduction:
Carboxylic compounds react with
(b)
Interpretation:
It should be determined that the product obtained from the reaction of Benzoic acid with
Concept introduction:
Carboxylic compounds react with
(c)
Interpretation:
It should be determined that the product obtained from the reaction of Methyl benzoate with
Concept introduction:
Carboxylic compounds react with
(d)
Interpretation:
It should be determined that the product obtained from the reaction of Pentatonic acid
with
Concept introduction:
Carboxylic compounds react with
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EBK ORGANIC CHEMISTRY
- Which could explain the stronger acidity of phenols compared to alcohols. Why? a.pi-electron delocalization b.steric effect c.hydrogen bonding d.hyperconjugationarrow_forwardWhat reaction converts benzoic acid to m-bromobenzoic acid? Alkylation Acylation Halogenation Hydrohalogenation Hydration Reduction Oxidation Nitration Sulfonationarrow_forwardConsider the structure of pent-2-ene, if it undergoes ozonolysis, which of the following final product is formed? a.Ethanal and Propanal b.Ethanal and Propanone c.CO2 and Propanal d.Ethanal and CO2arrow_forward
- Account for the fact that treating propenoic acid (acrylic acid) with HCl gives only 3-chloropropanoic acid.arrow_forwardIn the chemical synthesis of DNA and RNA, hydroxyl groups are normally converted to triphenylmethyl (trityl) ethers to protect the hydroxyl group from reaction with other reagents. Triphenylmethyl ethers are stable to aqueous base but are rapidly cleaved in aqueous acid. (a) Why are triphenylmethyl ethers so readily hydrolyzed by aqueous acid? (b) How might the structure of the triphenylmethyl group be modified to increase or decrease its acid sensitivity?arrow_forwardThe reaction of a ketone and excess methanol with an acid as a catalyst gives what product? A) Hemiacetal B) Di-ether C) Hemiketal D) Acetal E) Ketalarrow_forward
- Phosgene (COCl2) was used as a poison gas in World War I. What product would be formed from the reaction of phosgene with each of the followingreagents?a. one equivalent of methanol b. excess methanol c. excess propylamine d. excess waterarrow_forwardReactions of carbonyl compounds with hydride ion donors. a. Draw reaction of an aldehyde with sodium borohydride forms a primary alcohol. b. Draw reaction of a ketone with sodium borohydride forms a secondary alcohol.arrow_forwardIn the reaction of acetone with sodium borohydride, what is the geometry of the reaction intermediate that results from the nucleophilic addition of the hydride ion to the carbonyl group? A) trigonal planar B) tetrahedral C) linear D) octahedralarrow_forward
- The product of reaction between formaldehyde with 2-methyl propanal give 2,2-dimethyl-3-hydroxy propanal 2,2-dimethyl-3-hydroxy propanone 2,2-dimethyl-3-hydroxy propanoic acid 2,2-dimethyl-3-hydroxy propanol 4-phenyl-3-buten-2-one prepared from reaction between Benzaldehyde with acetic acid Benzaldehyde with acetaldehyde Benzaldehyde with formaldehyde Benzaldehyde with acetone Which predict product for reaction between heptane-6-one-1-al with sodium hydroxide * 1-(2-hydroxycyclopentyl) pentanone 1-(2-hydroxycyclopentyl) butanone 1-(2-hydroxycyclopentyl) ethanone 1-(2-hydroxycyclopentyl) propanonearrow_forwardAcetals are formed from the reaction of two alcohols with a carbonyl under acidic conditions. Acetal formation is faster with 1,2-ethanediol than with two methanol molecules. Choose the factor that explains the difference in reaction rates. A) The reaction with 1,2-ethanediol has a lower AH (enthalpy) of reaction. B) The reaction with 1,2-ethanediol has a higher AH (enthalpy) of reaction. C) The reaction with 1,2-ethanediol has a more favorable entropy of reaction.arrow_forwardWhich of the following ketone will produce propanoic acid only after oxidation by acidified potassium dichromate? Choices are a. diethyl ketone b. dimethyl ketone c. ethyl n-propyl ketone d. ethyl methyl ketonearrow_forward
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