General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 16, Problem 16.84P
Answer each question about phenylacetaldehyde, depicted in the ball-and-stick model, and Page 590 one of the components responsible for the fragrance of the plumeria flower.
a. Draw a skeletal structure for phenylacetaldehyde.
b. How many trigonal planar carbons are present in phenylacetaldehyde?
c. What product is formed when phenylacetaldehyde is treated with two equivalents of
d. What product is formed when phenylacetaldehyde is treated with one equivalent of hydrogen gas in the presence of a metal catalyst?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
1. What is the role of the acetic acid in the oxidation of Cyclohexanol to Cyclohexanone? Write the balanced chemical reaction between acetic acid and sodium hypochlorite.2. How do you neutralize the acetic acid regenerated in the reaction? Write the balanced chemical reaction.
6. Draw the correct structures for the following:
a. what is the correct structure of 3-methyl 1-pentyne?
b. what is the correct structure of butyl methyl amine?
c. what is the correct structure of 3-methyl 1-pentyne?
d. what is the correct structure of 2-methyl 2-butanol?
e. what is the correct structure of pentanoic acid?
5. What products would result from the following processes?
Write an equation for each reaction.
a. 2-Methyl-2-butanol is subjected to controlled oxidation.
b. 1-Propanol is heated to 140°C in the presence of sulfuric acid.
c. 3-Pentanol is subjected to controlled oxidation.
d. 3-Pentanol is heated to 180°C in the presence of sulfuric acid.
e. 1-Hexanol is subjected to an excess of oxidizing agent
Chapter 16 Solutions
General, Organic, & Biological Chemistry
Ch. 16.1 - Prob. 16.1PCh. 16.1 - Draw the structure of the three constitutional...Ch. 16.2 - Prob. 16.3PCh. 16.2 - Give the structure corresponding to each TUPAC...Ch. 16.2 - Prob. 16.5PCh. 16.2 - Prob. 16.6PCh. 16.2 - Give the structure corresponding to each name. a....Ch. 16.3 - Which compound in each pair has the higher boiling...Ch. 16.3 - Acetone and progesterone are two ketones that...Ch. 16.4 - Prob. 16.10P
Ch. 16.5 - What product is formed when each carbonyl compound...Ch. 16.5 - Prob. 16.12PCh. 16.5 - Prob. 16.13PCh. 16.6 - What alcohol is formed when each compound is...Ch. 16.6 - Prob. 16.15PCh. 16.6 - Prob. 16.16PCh. 16.7 - Prob. 16.17PCh. 16.7 - Prob. 16.18PCh. 16.8 - Prob. 16.19PCh. 16.8 - Prob. 16.20PCh. 16.8 - Prob. 16.21PCh. 16.8 - Label the three acetals in solanine, the toxic...Ch. 16.8 - Prob. 16.23PCh. 16.8 - Prob. 16.24PCh. 16 - Prob. 16.25PCh. 16 - Prob. 16.26PCh. 16 - Prob. 16.27PCh. 16 - Prob. 16.28PCh. 16 - Prob. 16.29PCh. 16 - Prob. 16.30PCh. 16 - Prob. 16.31PCh. 16 - Prob. 16.32PCh. 16 - Prob. 16.33PCh. 16 - Prob. 16.34PCh. 16 - Give an acceptable name for each ketone. a. b. c....Ch. 16 - Prob. 16.36PCh. 16 - Prob. 16.37PCh. 16 - Draw the structure corresponding to each name. a....Ch. 16 - Prob. 16.39PCh. 16 - Prob. 16.40PCh. 16 - Prob. 16.41PCh. 16 - Prob. 16.42PCh. 16 - Draw out the structure of benzaldehyde, including...Ch. 16 - Prob. 16.44PCh. 16 - Which compound in each pair has the higher boiling...Ch. 16 - Prob. 16.46PCh. 16 - Prob. 16.47PCh. 16 - Prob. 16.48PCh. 16 - Prob. 16.49PCh. 16 - Prob. 16.50PCh. 16 - Prob. 16.51PCh. 16 - Prob. 16.52PCh. 16 - Prob. 16.53PCh. 16 - Prob. 16.54PCh. 16 - Prob. 16.55PCh. 16 - Consider the following ball-and-stick model....Ch. 16 - Prob. 16.57PCh. 16 - Prob. 16.58PCh. 16 - Prob. 16.59PCh. 16 - Prob. 16.60PCh. 16 - Prob. 16.61PCh. 16 - Prob. 16.62PCh. 16 - Prob. 16.63PCh. 16 - Prob. 16.64PCh. 16 - Prob. 16.65PCh. 16 - Prob. 16.66PCh. 16 - Prob. 16.67PCh. 16 - Prob. 16.68PCh. 16 - Prob. 16.69PCh. 16 - Label the functional group(s) in each compound as...Ch. 16 - Prob. 16.71PCh. 16 - Prob. 16.72PCh. 16 - What acetal is formed when each aldehyde or ketone...Ch. 16 - What acetal is formed when each aldehyde or ketone...Ch. 16 - Prob. 16.75PCh. 16 - Prob. 16.76PCh. 16 - Prob. 16.77PCh. 16 - Prob. 16.78PCh. 16 - Prob. 16.79PCh. 16 - Prob. 16.80PCh. 16 - Prob. 16.81PCh. 16 - Prob. 16.82PCh. 16 - Prob. 16.83PCh. 16 - Answer each question about phenylacetaldehyde,...Ch. 16 - Prob. 16.85PCh. 16 - Prob. 16.86PCh. 16 - Prob. 16.87PCh. 16 - Prob. 16.88PCh. 16 - Three constitutional isomers of molecular formula...Ch. 16 - Identify A—C in the following reaction sequenceCh. 16 - Androsterone is a male sex hormone that controls...Ch. 16 - Prob. 16.92PCh. 16 - Prob. 16.93PCh. 16 - Prob. 16.94PCh. 16 - Prob. 16.95PCh. 16 - Paraldehyde, a hypnotic and sedative once commonly...Ch. 16 - Prob. 16.97PCh. 16 - Prob. 16.98PCh. 16 - Prob. 16.99CPCh. 16 - Prob. 16.100CP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- FLAVORANTS: Identify the aldehyde and ketone-containing flavoring compound from each following sources. Choose your best answer from the choices below A. 2-Octanone B. Citral C. Benzaldehyde D. Vanillin E. Cinnamaldehyde F. a-Damascone 1. Вerry 2. Mushroom 3. Lemongrass 4. Cinnamon 5. Almonds Idchyde or ketone formed froarrow_forward1. What are the substances present in the label of formaldehyde (formalin)? 2. What is the percentage composition of acetone in the nail polish remover? 3. According to your interview, what is/are the uses of formalin and acetone? A. Uses of Formalin- B. Uses of Acetone - 4. What type of bond is present in the two structures? 5. Why do you think aldehydes and ketones belong to the group of carbonyl containing compounds?arrow_forward9. Label the following reactions as: A. ionization of a carboxylic acid in water B. neutralization of a carboxylic acid with a base C. formation of an ester D. acid-catalyzed hydrolysis of an ester E. ionization of an amine in water F. neutralization of an amine with an acid G. formation of an amide H. hydrolysis of an amide CH3NH₂ + HCI CH3NH3 Cl CH3CH₂CNHCH 3 HOH CH₂COH CH3COH+ NaOH →→→→ CHICOH heat CHICOH CH3COH + CH3NH₂ CH₂COH CH3CH₂COCH₂CH₂CH + HOHH CH3CH₂COH + HOCH₂CH₂CH3 CHO + H₂O - CH3CO heat CHO CH₂CO *Na + HOH CH3NH₂ + H₂0 CH3NH3* + OH- + H3O+ CH3CH₂C + NH2CH3 R-H R-O-H CH3CNHCH3 + HOH R-N- I O CH₂COH CH3COH + HOCH3 CH3COCH3 + HOH сно сосни, O || R-C-R O 11 R-C-O-R Hydrocarbons Alcohols Amines Ketones Esters R-X R-O-R 0=0|0=0|0=0 R-C-H R-C-0-H R-C-N- I Alkyl halides Ethers Aldehydes Carboxylic Acids Amidesarrow_forward
- Draw the structures of organic compounds A and B. Omit all byproducts.arrow_forward1. What are the characteristics of a positive tollens test for adehydes? What is the oxidizing agent in tollens solutions? 2. What is the characteristics of a positive Benedict's test for aldehydes? What is the oxidizing agent in Benedict's solution?arrow_forwardWrite the complete chemical reaction and correct chemical formula and structure of the following: 1. Autooxidation of benzaldehyde 2. reaction between acetic acid and ethanol 3. reaction between aspirin and sodium hydroxide 4. reaction of acetone with methanolarrow_forward
- MCQ 6: The chemical reaction between carbonyl compounds and DNPH is an example of A. condensation reaction B. substitution reaction C. addition reaction D. elimination reactionarrow_forward1. Draw the following compounds. c. (Z)-2-methylpent-2-enol d. ethylpropanoatearrow_forwardAmino acids such as glycine are the building blocks of large molecules called proteins that give structure to muscle, tendon, hair, and nails. a. Explain why glycine does not actually exist in the form with all atoms uncharged, but actually exists as a salt called a zwitterion. b. What product is formed when glycine is treated with concentrated HCl? c. What product is formed when glycine is treated with NaOH?arrow_forward
- 1. An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B. Ketone C. Alcohol D. Ester 2. 3-Methylhexanal with K2Cr2O7 will yield: A. 3-Methyl-1-hexanol B. 3-Methylhexanoic acid C. 3-Methyl-1-hexanone D. 3-Methyl-1-hexanethiol 3. This is a reverse process of Hydration reaction: A. Oxidation reaction B. Reduction reaction C. Dehydration reaction D. Hydration reaction 4. Acetic acid reacts with a strong base forms: A. Salt B. Water C. Salt and Water D. No reaction 5. Ketones can be further oxidized with benedict's solution into: A. Alcohol B. Aldehyde C. Catalysts D. No reactionarrow_forward1arrow_forwardWhich of these statements is false regarding the following reaction? 1. LIAIH, 1. H* HO. ОН Select one: a. The reactant has a lower pKa than the product. b. The reagent can be synthesized in a reaction between an alcohol and an acid chloride. c. Product can react with SOCI2 to produce 1- chloropropane d. The carbon-oxygen bond in the product is longer than the carbon-oxygen bond of the carbonyl in the reactant.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
CBSE Class 12 Chemistry || Polymers || Full Chapter || By Shiksha House; Author: Best for NEET;https://www.youtube.com/watch?v=OxdJlS0xZ0Y;License: Standard YouTube License, CC-BY