
(a)
Interpretation:
Chemical equation for the conversion of given
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(a)

Explanation of Solution
Given carboxylic acid salt is sodium butanoate. The structure of sodium butanoate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
(b)
Interpretation:
Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(b)

Explanation of Solution
Given carboxylic acid salt is potassium oxalate. The structure of potassium oxalate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
(c)
Interpretation:
Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(c)

Explanation of Solution
Given carboxylic acid salt is calcium malonate. The structure of calcium malonate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
(d)
Interpretation:
Chemical equation for the conversion of given carboxylic acid salt to its parent carboxylic acid using
Concept Introduction:
The name of the carboxylic acid itself implies that it is acidic. Addition of carboxylic acid to water results in ionization. Hydrogen ion transfer occurs from carboxylic acid to water and hydronium ion is formed. Carboxylate ion is also formed due to the loss of hydrogen ion from carboxylic acid.
Carboxylate ion is the negative ion which is formed when one or more acidic protons are lost from carboxylic acid. Similar to carboxylic acid it reacts with strong base to form carboxylic acid salt and water.
Carboxylic acid salts when treated with a strong acid produces carboxylic acid as the product.
Carboxylic acid forms carboxylic acid salt by reacting with a strong base. The general reaction scheme for the formation of carboxylic acid salt is given as shown below,
The reverse of the above reaction is conversion of carboxylic acid salt to carboxylic acid. This is accomplished by using strong acid. The scheme is shown below,
From the above chemical equation it is found that the carboxylic acid salt reacts with strong acid to form carboxylic acid.
(d)

Explanation of Solution
Given carboxylic acid salt is sodium benzoate. The structure of sodium benzoate can be given as shown below,
Carboxylic acid sat is converted to carboxylic acid by reaction with strong acid. In the problem statement it is given that the strong acid is
Chemical equation for the conversion of given carboxylic acid salt to carboxylic acid using hydrochloric acid is written.
Want to see more full solutions like this?
Chapter 16 Solutions
General, Organic, and Biological Chemistry Seventh Edition
- Synthesize 2-Ethyl-3-methyloxirane from dimethyl(propyl)sulfonium iodide using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardSynthesize 2-Hydroxy-2-phenylacetonitrile from phenylmethanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardSynthesize N-Methylcyclohexylamine from cyclohexanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forward
- Synthesize N-Methylcyclohexylamine from cyclohexanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardIf possible, please provide the formula of the compound 3,3-dimethylbut-2-enal.arrow_forwardSynthesize 1,4-dibromobenzene from acetanilide (N-phenylacetamide) using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forward
- Indicate the products obtained by mixing (3-oxo-3-phenylpropyl)triphenylphosphonium bromide with sodium hydride.arrow_forwardWe mix N-ethyl-2-hexanamine with excess methyl iodide and followed by heating with aqueous Ag2O. Indicate the major products obtained.arrow_forwardIndicate the products obtained by mixing acetophenone with iodine and NaOH.arrow_forward
- Indicate the products obtained by mixing 2-Propanone and ethyllithium and performing a subsequent acid hydrolysis.arrow_forwardIndicate the products obtained if (E)-2-butenal and 3-oxo-butanenitrile are mixed with sodium ethoxide in ethanol.arrow_forwardQuestion 3 (4 points), Draw a full arrow-pushing mechanism for the following reaction Please draw all structures clearly. Note that this intramolecular cyclization is analogous to the mechanism for halohydrin formation. COH Br + HBr Brarrow_forward
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning




