General, Organic, and Biological Chemistry Seventh Edition
General, Organic, and Biological Chemistry Seventh Edition
7th Edition
ISBN: 9781305767867
Author: H. Stephan Stoker
Publisher: Cengage Learning
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Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 16, Problem 16.138EP , additional homework tip  1

From an IUPAC name, the structure of the thioester can be derived.  IUPAC name of thioester consists of two parts.  In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part.  Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name.  The only difference is the acyl part name.  The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 16, Problem 16.138EP , additional homework tip  2

From an IUPAC name, the structure of the thioester can be derived.  IUPAC name of thioester consists of two parts.  In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part.  Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name.  The only difference is the acyl part name.  The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 16, Problem 16.138EP , additional homework tip  3

From an IUPAC name, the structure of the thioester can be derived.  IUPAC name of thioester consists of two parts.  In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part.  Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name.  The only difference is the acyl part name.  The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

General, Organic, and Biological Chemistry Seventh Edition, Chapter 16, Problem 16.138EP , additional homework tip  4

From an IUPAC name, the structure of the thioester can be derived.  IUPAC name of thioester consists of two parts.  In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part.  Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name.  The only difference is the acyl part name.  The acyl part is named using the common name of thiocarboxylic acid.

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Chapter 16 Solutions

General, Organic, and Biological Chemistry Seventh Edition

Ch. 16.3 - Prob. 1QQCh. 16.3 - Prob. 2QQCh. 16.3 - Prob. 3QQCh. 16.4 - Prob. 1QQCh. 16.4 - Prob. 2QQCh. 16.4 - Prob. 3QQCh. 16.5 - Prob. 1QQCh. 16.5 - Prob. 2QQCh. 16.5 - Prob. 3QQCh. 16.6 - Prob. 1QQCh. 16.6 - Prob. 2QQCh. 16.7 - Prob. 1QQCh. 16.7 - Prob. 2QQCh. 16.7 - Prob. 3QQCh. 16.8 - Prob. 1QQCh. 16.8 - Prob. 2QQCh. 16.8 - Prob. 3QQCh. 16.8 - Prob. 4QQCh. 16.9 - Prob. 1QQCh. 16.9 - Prob. 2QQCh. 16.10 - Prob. 1QQCh. 16.10 - Prob. 2QQCh. 16.11 - Prob. 1QQCh. 16.11 - Prob. 2QQCh. 16.11 - Prob. 3QQCh. 16.12 - Prob. 1QQCh. 16.12 - Prob. 2QQCh. 16.12 - Prob. 3QQCh. 16.12 - Prob. 4QQCh. 16.13 - Prob. 1QQCh. 16.13 - Prob. 2QQCh. 16.14 - Prob. 1QQCh. 16.14 - Prob. 2QQCh. 16.14 - Prob. 3QQCh. 16.15 - Prob. 1QQCh. 16.15 - Prob. 2QQCh. 16.15 - Prob. 3QQCh. 16.16 - Prob. 1QQCh. 16.16 - Prob. 2QQCh. 16.16 - Prob. 3QQCh. 16.17 - Prob. 1QQCh. 16.17 - Prob. 2QQCh. 16.18 - Prob. 1QQCh. 16.18 - Prob. 2QQCh. 16.18 - Prob. 3QQCh. 16.19 - Prob. 1QQCh. 16.19 - Prob. 2QQCh. 16.19 - Prob. 3QQCh. 16.19 - Prob. 4QQCh. 16.20 - Prob. 1QQCh. 16.20 - Prob. 2QQCh. 16.20 - Prob. 3QQCh. 16.20 - Prob. 4QQCh. 16 - Prob. 16.1EPCh. 16 - Prob. 16.2EPCh. 16 - Prob. 16.3EPCh. 16 - Prob. 16.4EPCh. 16 - Prob. 16.5EPCh. 16 - Prob. 16.6EPCh. 16 - Prob. 16.7EPCh. 16 - Prob. 16.8EPCh. 16 - Prob. 16.9EPCh. 16 - Prob. 16.10EPCh. 16 - Prob. 16.11EPCh. 16 - Prob. 16.12EPCh. 16 - Prob. 16.13EPCh. 16 - Prob. 16.14EPCh. 16 - Prob. 16.15EPCh. 16 - Prob. 16.16EPCh. 16 - Prob. 16.17EPCh. 16 - Prob. 16.18EPCh. 16 - Prob. 16.19EPCh. 16 - Prob. 16.20EPCh. 16 - Prob. 16.21EPCh. 16 - Prob. 16.22EPCh. 16 - Prob. 16.23EPCh. 16 - Prob. 16.24EPCh. 16 - Prob. 16.25EPCh. 16 - Prob. 16.26EPCh. 16 - Prob. 16.27EPCh. 16 - Prob. 16.28EPCh. 16 - Prob. 16.29EPCh. 16 - Prob. 16.30EPCh. 16 - Prob. 16.31EPCh. 16 - Prob. 16.32EPCh. 16 - Prob. 16.33EPCh. 16 - Prob. 16.34EPCh. 16 - Prob. 16.35EPCh. 16 - Prob. 16.36EPCh. 16 - Prob. 16.37EPCh. 16 - Prob. 16.38EPCh. 16 - Prob. 16.39EPCh. 16 - Prob. 16.40EPCh. 16 - Determine the maximum number of hydrogen bonds...Ch. 16 - Prob. 16.42EPCh. 16 - Prob. 16.43EPCh. 16 - Prob. 16.44EPCh. 16 - Prob. 16.45EPCh. 16 - Prob. 16.46EPCh. 16 - Prob. 16.47EPCh. 16 - Prob. 16.48EPCh. 16 - Prob. 16.49EPCh. 16 - Prob. 16.50EPCh. 16 - Prob. 16.51EPCh. 16 - Prob. 16.52EPCh. 16 - Prob. 16.53EPCh. 16 - Prob. 16.54EPCh. 16 - Prob. 16.55EPCh. 16 - Prob. 16.56EPCh. 16 - Give the IUPAC name for each of the following...Ch. 16 - Give the IUPAC name for each of the following...Ch. 16 - Prob. 16.59EPCh. 16 - Give the common name for each of the carboxylic...Ch. 16 - Prob. 16.61EPCh. 16 - Write a chemical equation for the preparation of...Ch. 16 - Prob. 16.63EPCh. 16 - Prob. 16.64EPCh. 16 - Prob. 16.65EPCh. 16 - Prob. 16.66EPCh. 16 - Prob. 16.67EPCh. 16 - Prob. 16.68EPCh. 16 - Prob. 16.69EPCh. 16 - Prob. 16.70EPCh. 16 - Prob. 16.71EPCh. 16 - Prob. 16.72EPCh. 16 - Prob. 16.73EPCh. 16 - Prob. 16.74EPCh. 16 - Prob. 16.75EPCh. 16 - Prob. 16.76EPCh. 16 - Prob. 16.77EPCh. 16 - Prob. 16.78EPCh. 16 - Prob. 16.79EPCh. 16 - Prob. 16.80EPCh. 16 - Prob. 16.81EPCh. 16 - Prob. 16.82EPCh. 16 - Prob. 16.83EPCh. 16 - Prob. 16.84EPCh. 16 - Prob. 16.85EPCh. 16 - Prob. 16.86EPCh. 16 - Prob. 16.87EPCh. 16 - Prob. 16.88EPCh. 16 - Prob. 16.89EPCh. 16 - Prob. 16.90EPCh. 16 - Prob. 16.91EPCh. 16 - Prob. 16.92EPCh. 16 - Assign an IUPAC name to each of the following...Ch. 16 - Prob. 16.94EPCh. 16 - Prob. 16.95EPCh. 16 - Prob. 16.96EPCh. 16 - Prob. 16.97EPCh. 16 - Prob. 16.98EPCh. 16 - Prob. 16.99EPCh. 16 - Prob. 16.100EPCh. 16 - How many carbon atoms are present in a molecule of...Ch. 16 - Prob. 16.102EPCh. 16 - Prob. 16.103EPCh. 16 - Prob. 16.104EPCh. 16 - Prob. 16.105EPCh. 16 - Prob. 16.106EPCh. 16 - Prob. 16.107EPCh. 16 - Prob. 16.108EPCh. 16 - Prob. 16.109EPCh. 16 - Prob. 16.110EPCh. 16 - Prob. 16.111EPCh. 16 - Prob. 16.112EPCh. 16 - Prob. 16.113EPCh. 16 - Prob. 16.114EPCh. 16 - Prob. 16.115EPCh. 16 - Prob. 16.116EPCh. 16 - Prob. 16.117EPCh. 16 - Prob. 16.118EPCh. 16 - Prob. 16.119EPCh. 16 - Prob. 16.120EPCh. 16 - Prob. 16.121EPCh. 16 - Prob. 16.122EPCh. 16 - Prob. 16.123EPCh. 16 - Prob. 16.124EPCh. 16 - Prob. 16.125EPCh. 16 - Prob. 16.126EPCh. 16 - Prob. 16.127EPCh. 16 - Prob. 16.128EPCh. 16 - Prob. 16.129EPCh. 16 - Prob. 16.130EPCh. 16 - Prob. 16.131EPCh. 16 - Prob. 16.132EPCh. 16 - Prob. 16.133EPCh. 16 - Prob. 16.134EPCh. 16 - Prob. 16.135EPCh. 16 - Prob. 16.136EPCh. 16 - Prob. 16.137EPCh. 16 - Prob. 16.138EPCh. 16 - Prob. 16.139EPCh. 16 - Prob. 16.140EPCh. 16 - Prob. 16.141EPCh. 16 - Prob. 16.142EPCh. 16 - Prob. 16.143EPCh. 16 - Prob. 16.144EPCh. 16 - Prob. 16.145EPCh. 16 - Prob. 16.146EPCh. 16 - Prob. 16.147EPCh. 16 - Prob. 16.148EPCh. 16 - Draw a condensed structural formula for the...Ch. 16 - Prob. 16.150EPCh. 16 - Prob. 16.151EPCh. 16 - Prob. 16.152EPCh. 16 - Prob. 16.153EPCh. 16 - Prob. 16.154EPCh. 16 - Prob. 16.155EPCh. 16 - Prob. 16.156EPCh. 16 - Prob. 16.157EPCh. 16 - Prob. 16.158EPCh. 16 - Prob. 16.159EPCh. 16 - Prob. 16.160EPCh. 16 - Prob. 16.161EPCh. 16 - Prob. 16.162EPCh. 16 - Prob. 16.163EPCh. 16 - Prob. 16.164EP
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