IUPAC name for the carboxylic acid has to be given. Concept Introduction: For naming a carboxylic acid in IUPAC nomenclature , the suffix “-oic” is added to the parent alkane name. IUPAC rules for naming a carboxylic acid: The longest parent carbon chain is identified that includes the carboxyl group. The parent chain name is changed by replacing the suffix “-e” with “-oic acid”. Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde , the carboxyl carbon is always numbered 1. The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name. If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix. If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

Question

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Answer 1

Question

Chapter 16, Problem 16.20EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for carboxylic acid, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the four structures. Compound C Possible conformations (circle one): Дет

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Answer 2

Question

Chapter 16, Problem 16.20EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for carboxylic acid, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

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Answer 3

Question

Chapter 16, Problem 16.20EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for carboxylic acid, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

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Answer 4

Question

Chapter 16, Problem 16.20EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for carboxylic acid, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

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Answer 5

Chapter 16, Problem 16.20EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for carboxylic acid, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

Answer 6

Chapter 16, Problem 16.20EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

Answer 7

Chapter 16, Problem 16.20EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

If the compound contains two carboxyl groups, then suffix “-dioic acid” is added after the parent alkane name.

Answer 8

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for carboxylic acid, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

Answer 9

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for carboxylic acid, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

Answer 10

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

Answer 11

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

Answer 12

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

Answer 13

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the carboxylic acid has to be given.

Concept Introduction:

For naming a carboxylic acid in IUPAC nomenclature, the suffix “-oic” is added to the parent alkane name.

IUPAC rules for naming a carboxylic acid:

The longest parent carbon chain is identified that includes the carboxyl group.

The parent chain name is changed by replacing the suffix “-e” with “-oic acid”.

Numbering is done in a way that the carboxyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carboxyl carbon is always numbered 1.

The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

If the carboxyl functional group is attached to a ring of carbon atoms, the ring is named and “-carboxylic acid” is added as suffix.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains the IUPAC name for the carboxylic acid.

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Chapter 16 Solutions