IUPAC name for the given compound has to be assigned. Concept Introduction: For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom. Rules to obtain IUPAC name and common name for an acid anhydride: IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride. IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

Question

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.148EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiCl

Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOH

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.148EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.148EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.148EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

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Answer 5

Chapter 16, Problem 16.148EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

Answer 6

Chapter 16, Problem 16.148EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

Answer 7

Chapter 16, Problem 16.148EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

Answer 8

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

Answer 9

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

Answer 10

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

Answer 11

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group

Rules to obtain IUPAC name and common name for an acid chloride:

IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.

Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.

Answer 12

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

Answer 13

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given compound has to be assigned.

Concept Introduction:

For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.

Rules to obtain IUPAC name and common name for an acid anhydride:

IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.

IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

Answer 14

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Answer 25

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that IUPAC name for the given compound has to be assigned.

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Chapter 16 Solutions