Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 16, Problem 16.15P
16-15 There are eight primary
(a) Name and draw a structural formula for each amine.
(b > Which of these amines are chiral?
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(a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.
The five parts of question 16 relate to the following three molecules:
N-H
А в с
A
(a) Which of the three molecules above are structural isomers?
(b) Which of the molecules contains a carbon with linear geometry?
(c) Which molecule contains a tertiary amine?
(d) Which molecule only contains sp³ hybridized atoms (not including hydrogen)?
(e)
Which molecule is chiral? Circle the stereocentre in this molecule.
Draw and name compounds that meet these descriptions:(a) Three different amides with the formula C6H13NO(b) Three different esters with the formula C5H10O2
Chapter 16 Solutions
Introduction to General, Organic and Biochemistry
Ch. 16.1 - Problem 16-1 How many hydrogen atoms does...Ch. 16.2 - Problem 16-2 Write a structural formula for each...Ch. 16.2 - Prob. 16.3PCh. 16.4 - Problem 16-4 Select the stronger base from each...Ch. 16.5 - Prob. 16.5PCh. 16 - 16-6 Answer true or false. te/7-Butylamine is a 3°...Ch. 16 - Prob. 16.7PCh. 16 - Prob. 16.8PCh. 16 - 16-9 In what way are pyridine and pyrimidine...Ch. 16 - Prob. 16.10P
Ch. 16 - Prob. 16.11PCh. 16 - Prob. 16.12PCh. 16 - 16-13 Classify each amino group as primary,...Ch. 16 - Prob. 16.14PCh. 16 - 16-15 There are eight primary amines with the...Ch. 16 - Prob. 16.16PCh. 16 - 16-17 Propylamine (bp 48°C), ethylmethylamine (bp...Ch. 16 - 16-18 Account for the fact that 1-butanamine (bp...Ch. 16 - 16-19 2-Me thy 1 propane (bp -12°C), 2-propanol...Ch. 16 - Prob. 16.20PCh. 16 - Prob. 16.21PCh. 16 - Prob. 16.22PCh. 16 - Prob. 16.23PCh. 16 - Prob. 16.24PCh. 16 - Prob. 16.25PCh. 16 - 16-26 The p/fb of amphetamine is approximately 3.2...Ch. 16 - 16-27 Guanidine, p/Ca 13.6, is a very strong base,...Ch. 16 - 16-28 Following is the structural formula of...Ch. 16 - Prob. 16.29PCh. 16 - Prob. 16.30PCh. 16 - Prob. 16.31PCh. 16 - 16*32 Many tumors of the breast are correlated...Ch. 16 - Prob. 16.33PCh. 16 - Prob. 16.34PCh. 16 - 16-35 (Chemical Connections 16B ) What is an...Ch. 16 - Prob. 16.36PCh. 16 - Prob. 16.37PCh. 16 - Prob. 16.38PCh. 16 - Prob. 16.39PCh. 16 - Prob. 16.40PCh. 16 - Prob. 16.41PCh. 16 - Prob. 16.42PCh. 16 - Prob. 16.43PCh. 16 - Prob. 16.44PCh. 16 - Prob. 16.45PCh. 16 - 16-46 Arrange these three compounds in order of...Ch. 16 - Prob. 16.47PCh. 16 - Prob. 16.48PCh. 16 - Prob. 16.49PCh. 16 - Prob. 16.50PCh. 16 - Prob. 16.51PCh. 16 - Prob. 16.52PCh. 16 - Prob. 16.53PCh. 16 - 16-54 Several poisonous plants, including Atropa...Ch. 16 - Prob. 16.55PCh. 16 - Prob. 16.56PCh. 16 - Prob. 16.57PCh. 16 - 16-58 Following is a structural formula of...Ch. 16 - Prob. 16.59P
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- Draw structural formulas for each of the following: (a) The four primary (1°) amines with the molecular formula C4H11N. (b) The three secondary (2°) amines with the molecular formula C4H11N. (c) The one tertiary (3°) amine with the molecular formula C4H11N.arrow_forwardBecause amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forwardDraw the skeletal ("line") structure of a secondary amine with 4 carbon atoms, and no double or triple bonds.arrow_forward
- Compounds that contain an N-H group associate by hydrogen bonding. (a) Do you expect this association to be stronger or weaker than that of compounds containing an O-H group? (b) Based on your answer to part (a), which would you predict to have the higher boiling point, 1-butanol or 1-butanamine?arrow_forwardThe amino acid serine is shown below. What functional groups are present in this molecule as drawn? O || H₂N-CH-C-OH I CH₂ I OH (A) ketone, carboxylic acid, amide (B) ester, alcohol, amine (C) carboxylic acid, amine, alcohol (D) ester, amide, alcoholarrow_forwardIndicate whether each statement is true or false: (a) Fat molecules contain amide bonds. (b) Phosphoplipids can be zwitterions. (c) Phospholipids form bilayers in water in order to have their long hydrophobic tails interact favorably with each other, leaving their polar heads to the aqueous environment.arrow_forward
- draw 2 isomers tertiary amine with the formula C5H13Narrow_forward< app.101edu.co Classify and describe the properties of the following nitrogen containing compound. O CI O + Question 13.a of 25 CH3 N Classify the following amine. H CH3 A) primary amine B) secondary amine C) tertiary amine @=J D) tertiary amine salt E) quaternary ammonium saltarrow_forwardClassify each compound (a)–(f) as one of the following: (i) amide, (ii) ester, or(iii) carboxylic acid. (a) CH3COOCH3 (b) RCONHR (c) C6H5COOHarrow_forward
- (i) The table shows the structures and boiling points of three amines, which are structural isomers of C3H,N. Amine CH,CH,CH,NH, (CH,),CHNH, (CH,),N Skeletal formula `NH, NH2 Boiling point/°c 48-49°C 33-34 °C 3-4°C Explain the difference in the boiling points of the three amines. ....arrow_forwardWrite structural formulas for these amines. (a) Isobutylaminearrow_forwardUsing the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.arrow_forward
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