(a) Interpretation: To name and draw a structural formula for each amine formed from C 4 H 11 N . Concept Introduction: For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

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Answer 1

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Because amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.

Write the common name for each amine. HỌC—N—CH,CH3 H₂C-CH₂-CH₂-CH₂ Ethylbutylamine common name: Incorrect HC—CH,—N—CH,—CHy CH₂ CH3 diethylethylamine common name: Incorrect These compounds are tertiary amines.

Explain why CH3 CH2 CH2NH2 is a Brønsted base. Its water solutions are basic. All substances containing nitrogen atoms are Brønsted bases. This amine is a proton donor. This amine can ассеpt a proton from a proton donor.

Answer 2

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Answer 3

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Answer 4

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Answer 5

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

Answer 6

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Answer 7

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Answer 8

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Answer 9

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Answer 10

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

Answer 11

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16.1 - Problem 16-1 How many hydrogen atoms does...Ch. 16.2 - Problem 16-2 Write a structural formula for each...Ch. 16.2 - Prob. 16.3P Ch. 16.4 - Problem 16-4 Select the stronger base from each...Ch. 16.5 - Prob. 16.5P Ch. 16 - 16-6 Answer true or false. te/7-Butylamine is a 3°...Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - 16-9 In what way are pyridine and pyrimidine...Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that the constitutional isomers have the same molecular formula but differ in the connectivity of their atoms.

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Chapter 16 Solutions

Solution Summary: The author explains that the constitutional isomers have the same molecular formula but differ in the connectivity of their atoms.

(c) Interpretation: To select the amines among the drawn structures which are chiral. Concept Introduction: Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

Want to see the full answer?

Chapter 16 Solutions

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.