(a) Interpretation: To name and draw a structural formula for each amine formed from C 4 H 11 N . Concept Introduction: For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

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Answer 1

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Part VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?

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Answer 2

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Answer 3

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Answer 4

Question

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Answer 5

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

Answer 6

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Answer 7

Chapter 16, Problem 16.14P

Interpretation Introduction

(a)

Interpretation:

To name and draw a structural formula for each amine formed from C4H11N.

Concept Introduction:

For a given molecular formula, there will be many possible structural formulas. The constitutional isomers have the same molecular formula but differ in the connectivity of their atoms. These are called structural isomers.

Answer 8

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Answer 9

Interpretation Introduction

(b)

Interpretation:

To classify each constitutional isomer drawn as primary, secondary or tertiary.

Concept Introduction:

If nitrogen atom of an amine is connected to one carbon then it is called a primary amine. If the nitrogen atom of an amine is connected to two carbons, then it is called a secondary amine. If the nitrogen atom of an amine is connected to three carbons, then it is called a tertiary amine.

Answer 10

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

Answer 11

Interpretation Introduction

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16.1 - Problem 16-1 How many hydrogen atoms does...Ch. 16.2 - Problem 16-2 Write a structural formula for each...Ch. 16.2 - Prob. 16.3P Ch. 16.4 - Problem 16-4 Select the stronger base from each...Ch. 16.5 - Prob. 16.5P Ch. 16 - 16-6 Answer true or false. te/7-Butylamine is a 3°...Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - 16-9 In what way are pyridine and pyrimidine...Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that the constitutional isomers have the same molecular formula but differ in the connectivity of their atoms.

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Chapter 16 Solutions

Solution Summary: The author explains that the constitutional isomers have the same molecular formula but differ in the connectivity of their atoms.

(c) Interpretation: To select the amines among the drawn structures which are chiral. Concept Introduction: Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.

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Chapter 16 Solutions

(c)

Interpretation:

To select the amines among the drawn structures which are chiral.

Concept Introduction:

Chirality is the property by which the actual and mirror images have their resemblance. Amines are said to be chiral if all the substituents attached to it are different.