(a) Interpretation: The strongest acid among the following should be identified: CH 3 OH, CH 3 SH, (CH 3 ) 2 NH. Concept Introduction: The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

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Answer 1

Question

Chapter 16, Problem 16.47P

Interpretation Introduction

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Interpretation Introduction

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

Interpretation Introduction

(c)

Interpretation:

The compound with highest boiling point should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The temperature at which the system changes its state from liquid to vapor is known as boiling point. It depends on the size and bonding within the molecules. Higher the size, higher will be the boiling point. Also, stronger the intermolecular interaction within in the compound higher will be the boiling point.

Interpretation Introduction

(d)

Interpretation:

The compound with the strongest intermolecular hydrogen bonds in the pure state should be identified.

Concept Introduction:

A hydrogen bond is formed when hydrogen atom bonded with an electronegative atom interacts weakly with other electronegative atom which is present in the vicinity of another electronegative atom.

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1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)

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Answer 2

Question

Chapter 16, Problem 16.47P

Interpretation Introduction

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Interpretation Introduction

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

Interpretation Introduction

(c)

Interpretation:

The compound with highest boiling point should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The temperature at which the system changes its state from liquid to vapor is known as boiling point. It depends on the size and bonding within the molecules. Higher the size, higher will be the boiling point. Also, stronger the intermolecular interaction within in the compound higher will be the boiling point.

Interpretation Introduction

(d)

Interpretation:

The compound with the strongest intermolecular hydrogen bonds in the pure state should be identified.

Concept Introduction:

A hydrogen bond is formed when hydrogen atom bonded with an electronegative atom interacts weakly with other electronegative atom which is present in the vicinity of another electronegative atom.

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Answer 3

Question

Chapter 16, Problem 16.47P

Interpretation Introduction

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Interpretation Introduction

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

Interpretation Introduction

(c)

Interpretation:

The compound with highest boiling point should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The temperature at which the system changes its state from liquid to vapor is known as boiling point. It depends on the size and bonding within the molecules. Higher the size, higher will be the boiling point. Also, stronger the intermolecular interaction within in the compound higher will be the boiling point.

Interpretation Introduction

(d)

Interpretation:

The compound with the strongest intermolecular hydrogen bonds in the pure state should be identified.

Concept Introduction:

A hydrogen bond is formed when hydrogen atom bonded with an electronegative atom interacts weakly with other electronegative atom which is present in the vicinity of another electronegative atom.

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Answer 4

Question

Chapter 16, Problem 16.47P

Interpretation Introduction

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Interpretation Introduction

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

Interpretation Introduction

(c)

Interpretation:

The compound with highest boiling point should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The temperature at which the system changes its state from liquid to vapor is known as boiling point. It depends on the size and bonding within the molecules. Higher the size, higher will be the boiling point. Also, stronger the intermolecular interaction within in the compound higher will be the boiling point.

Interpretation Introduction

(d)

Interpretation:

The compound with the strongest intermolecular hydrogen bonds in the pure state should be identified.

Concept Introduction:

A hydrogen bond is formed when hydrogen atom bonded with an electronegative atom interacts weakly with other electronegative atom which is present in the vicinity of another electronegative atom.

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Answer 5

Chapter 16, Problem 16.47P

Interpretation Introduction

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Interpretation Introduction

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

Interpretation Introduction

(c)

Interpretation:

The compound with highest boiling point should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The temperature at which the system changes its state from liquid to vapor is known as boiling point. It depends on the size and bonding within the molecules. Higher the size, higher will be the boiling point. Also, stronger the intermolecular interaction within in the compound higher will be the boiling point.

Interpretation Introduction

(d)

Interpretation:

The compound with the strongest intermolecular hydrogen bonds in the pure state should be identified.

Concept Introduction:

A hydrogen bond is formed when hydrogen atom bonded with an electronegative atom interacts weakly with other electronegative atom which is present in the vicinity of another electronegative atom.

Answer 6

Chapter 16, Problem 16.47P

Interpretation Introduction

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Answer 7

Chapter 16, Problem 16.47P

Interpretation Introduction

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The compound with highest boiling point should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The temperature at which the system changes its state from liquid to vapor is known as boiling point. It depends on the size and bonding within the molecules. Higher the size, higher will be the boiling point. Also, stronger the intermolecular interaction within in the compound higher will be the boiling point.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The compound with highest boiling point should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The temperature at which the system changes its state from liquid to vapor is known as boiling point. It depends on the size and bonding within the molecules. Higher the size, higher will be the boiling point. Also, stronger the intermolecular interaction within in the compound higher will be the boiling point.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The compound with the strongest intermolecular hydrogen bonds in the pure state should be identified.

Concept Introduction:

A hydrogen bond is formed when hydrogen atom bonded with an electronegative atom interacts weakly with other electronegative atom which is present in the vicinity of another electronegative atom.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The compound with the strongest intermolecular hydrogen bonds in the pure state should be identified.

Concept Introduction:

A hydrogen bond is formed when hydrogen atom bonded with an electronegative atom interacts weakly with other electronegative atom which is present in the vicinity of another electronegative atom.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 16.1 - Problem 16-1 How many hydrogen atoms does...Ch. 16.2 - Problem 16-2 Write a structural formula for each...Ch. 16.2 - Prob. 16.3P Ch. 16.4 - Problem 16-4 Select the stronger base from each...Ch. 16.5 - Prob. 16.5P Ch. 16 - 16-6 Answer true or false. te/7-Butylamine is a 3°...Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - 16-9 In what way are pyridine and pyrimidine...Ch. 16 - Prob. 16.10P

(a) Interpretation: The strongest acid among the following should be identified: CH 3 OH, CH 3 SH, (CH 3 ) 2 NH. Concept Introduction: The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Solution Summary: The author explains that the acidity of any compound is higher when the compound has a higher electron donating capacity. The temperature at which the system changes its state from liquid to vapor is known as boiling point.

(a)

Interpretation:

The strongest acid among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

(b)

Interpretation:

The strongest base among the following should be identified:

CH₃ OH, CH₃ SH, (CH₃ )₂ NH.

Concept Introduction:

The basicity of any compound is higher when the compound has a higher electron donating ability or a higher proton accepting capacity.

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Chapter 16 Solutions

(a) Interpretation: The strongest acid among the following should be identified: CH 3 OH, CH 3 SH, (CH 3 ) 2 NH. Concept Introduction: The acidity of any compound is higher when the compound has a higher electron withdraw or a higher proton donating capacity.

Solution Summary: The author explains that the acidity of any compound is higher when the compound has a higher electron donating capacity. The temperature at which the system changes its state from liquid to vapor is known as boiling point.