Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 15, Problem 42QRT
Calculate the volume of 0.225-M NaOH required to titrate to the equivalence point for each of these samples.
- (a) 20.0 mL of 0.315-M HBr
- (b) 30.0 mL of 0.250-M HClO4
- (c) 6.00 g of concentrated acetic acid, CH3COOH, which is 99.7% pure
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Consider the titration of 36.0 mL of 0.117 M ammonia with 0.0752 M HCl. (See the Acid-Base Table.)
(a) How many mL of HCl are required to reach the equivalence point?5.60 mL(b) What is the pH at the equivalence point? 5.30(c) What is the pH of the solution after the addition of 15.7 mL of acid? (d) What is the pH of the solution after the addition of 82.9 mL of acid?
only need part c and d please
In the titration of 60.0 mL of 1.0 M methylamine, CH3NH₂ (K₁ = 4.4 x 10-4), with 0.50 M HCI, calculate the pH under the
following conditions.
(a) after 0.00 mL of 0.50 M HCI has been added
4.0
(b) after 20.0 mL of 0.50 M HCI has been added
4.0✔
(c) after 60.0 mL of 0.50 M HCI has been added
4.0✔
(d) at the stoichiometric point
4.0✔
(e) after 200.00 mL of 0.50 M HCI has been added
4.0
31. (a) Calculate the pH of a mixture containing 0.1 M propanoic acid (CH3CH₂COOH) and
0.050 M sodium propanoate (CH3CH₂COONa)
(b) Determine the change in pH that occurs when 0.15 mol solid NaOH is added to 1.00
litre of the buffered solution.
32. (a) Calculate the pH of a buffer solution produced by adding 3.28 g of sodium ethanoate
to 1 dm3 of 0.01 M of ethanoic acid (Ka = 1.84x 10-5 at 300K)
(b) calculate the pH of this buffer if 10 cm3 of 0.1 M HCl are now added
Chapter 15 Solutions
Chemistry: The Molecular Science
Ch. 15.1 - Predict whether 1.0 L of each solution is a...Ch. 15.1 - Calculate the pH of blood containing 0.0020-M...Ch. 15.1 - Prob. 15.2ECh. 15.1 -
Calculate the ratio of [] to [] in blood at a...Ch. 15.1 - Use the data in Table 15.1 to select a conjugate...Ch. 15.1 -
Calculate the mole ratio of sodium acetate and...Ch. 15.1 - Calculate the pH of these buffers.
Ch. 15.1 - If an abnormally high CO2 concentration is present...Ch. 15.1 - Calculate the minimum mass (g) of KOH that would...Ch. 15.2 - For the titration of 50.0 mL of 0.100-M HCl with...
Ch. 15.2 - Draw the titration curve for the titration of 50.0...Ch. 15.2 - Use the Ka expression and value for acetic acid to...Ch. 15.2 - Explain why the curve for the titration of acetic...Ch. 15.4 - Write the Ksp expression for each of these...Ch. 15.4 - The Ksp of AgBr at 100 C is 5 1010. Calculate the...Ch. 15.4 - A saturated solution of silver oxalate. Ag2C2O4....Ch. 15.4 - Prob. 15.9CECh. 15.5 - Consider 0.0010-M solutions of these sparingly...Ch. 15.5 - Prob. 15.11PSPCh. 15.5 - Calculate the solubility of PbCl2 in (a) pure...Ch. 15.5 - Prob. 15.13PSPCh. 15.6 - (a) Determine whether AgCl precipitates from a...Ch. 15.6 - Prob. 15.15PSPCh. 15 - Prob. 1SPCh. 15 - Choose a weak-acid/weak-base conjugate pair from...Ch. 15 - Prob. 4SPCh. 15 - Define the term buffer capacity.Ch. 15 - What is the difference between the end point and...Ch. 15 - What are the characteristics of a good acid-base...Ch. 15 - A strong acid is titrated with a strong base, such...Ch. 15 - Repeat the description for Question 4, but use a...Ch. 15 - Use Le Chatelier’s principle to explain why PbCl2...Ch. 15 - Describe what a complex ion is and give an...Ch. 15 - Define the term “amphoteric”.
Ch. 15 - Distinguish between the ion product (Q) expression...Ch. 15 - Describe at least two ways that the solubility of...Ch. 15 - Briefly describe how a buffer solution can control...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Many natural processes can be studied in the...Ch. 15 - Which of these combinations is the best to buffer...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Calculate the mass of sodium acetate, NaCH3COO,...Ch. 15 - Calculate the mass in grams of ammonium chloride,...Ch. 15 - A buffer solution can be made from benzoic acid,...Ch. 15 - A buffer solution is prepared from 5.15 g NH4NO3...Ch. 15 - You dissolve 0.425 g NaOH in 2.00 L of a solution...Ch. 15 - A buffer solution is prepared by adding 0.125 mol...Ch. 15 - If added to 1 L of 0.20-M acetic acid, CH3COOH,...Ch. 15 - If added to 1 L of 0.20-M NaOH, which of these...Ch. 15 - Calculate the pH change when 10.0 mL of 0.100-M...Ch. 15 - Prob. 29QRTCh. 15 - Prob. 30QRTCh. 15 - Prob. 31QRTCh. 15 - The titration curves for two acids with the same...Ch. 15 - Explain why it is that the weaker the acid being...Ch. 15 - Prob. 34QRTCh. 15 - Consider all acid-base indicators discussed in...Ch. 15 - Which of the acid-base indicators discussed in...Ch. 15 - It required 22.6 mL of 0.0140-M Ba(OH)2 solution...Ch. 15 - It took 12.4 mL of 0.205-M H2SO4 solution to...Ch. 15 - Vitamin C is a monoprotic acid. To analyze a...Ch. 15 - An acid-base titration was used to find the...Ch. 15 - Calculate the volume of 0.150-M HCl required to...Ch. 15 - Calculate the volume of 0.225-M NaOH required to...Ch. 15 - Prob. 43QRTCh. 15 - Prob. 44QRTCh. 15 - Prob. 45QRTCh. 15 - Explain why rain with a pH of 6.7 is not...Ch. 15 - Identify two oxides that are key producers of acid...Ch. 15 - Prob. 48QRTCh. 15 - Prob. 49QRTCh. 15 - Prob. 50QRTCh. 15 - Prob. 51QRTCh. 15 - A saturated solution of silver arsenate, Ag3AsO4,...Ch. 15 - Prob. 53QRTCh. 15 - Prob. 54QRTCh. 15 - Prob. 55QRTCh. 15 - Prob. 56QRTCh. 15 - Prob. 57QRTCh. 15 - Prob. 58QRTCh. 15 - Prob. 59QRTCh. 15 - Prob. 60QRTCh. 15 - Prob. 61QRTCh. 15 - Prob. 62QRTCh. 15 - Prob. 63QRTCh. 15 - Prob. 64QRTCh. 15 - Predict what effect each would have on this...Ch. 15 - Prob. 66QRTCh. 15 - Prob. 67QRTCh. 15 - The solubility of Mg(OH)2 in water is...Ch. 15 - Prob. 69QRTCh. 15 - Prob. 70QRTCh. 15 - Prob. 71QRTCh. 15 - Prob. 72QRTCh. 15 - Write the chemical equation for the formation of...Ch. 15 - Prob. 74QRTCh. 15 - Prob. 75QRTCh. 15 - Prob. 76QRTCh. 15 - Prob. 77QRTCh. 15 - Prob. 78QRTCh. 15 - Prob. 79QRTCh. 15 - Prob. 80QRTCh. 15 - Prob. 81QRTCh. 15 - Solid sodium fluoride is slowly added to an...Ch. 15 - Prob. 83QRTCh. 15 - Prob. 84QRTCh. 15 - A buffer solution was prepared by adding 4.95 g...Ch. 15 - Prob. 86QRTCh. 15 - Prob. 87QRTCh. 15 - Prob. 88QRTCh. 15 - Prob. 89QRTCh. 15 - Which of these buffers involving a weak acid HA...Ch. 15 - Prob. 91QRTCh. 15 - Prob. 92QRTCh. 15 - When 40.00 mL of a weak monoprotic acid solution...Ch. 15 - Each of the solutions in the table has the same...Ch. 15 - Prob. 95QRTCh. 15 - Prob. 97QRTCh. 15 - The average normal concentration of Ca2+ in urine...Ch. 15 - Explain why even though an aqueous acetic acid...Ch. 15 - Prob. 100QRTCh. 15 - Prob. 101QRTCh. 15 - Prob. 102QRTCh. 15 - Prob. 103QRTCh. 15 - Prob. 104QRTCh. 15 - Apatite, Ca5(PO4)3OH, is the mineral in teeth.
On...Ch. 15 - Calculate the maximum concentration of Mg2+...Ch. 15 - Prob. 107QRTCh. 15 - Prob. 108QRTCh. 15 - The grid has six lettered boxes, each of which...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Prob. 112QRTCh. 15 - Prob. 113QRTCh. 15 - Prob. 114QRTCh. 15 - Prob. 115QRTCh. 15 - You want to prepare a pH 4.50 buffer using sodium...Ch. 15 - Prob. 117QRTCh. 15 - Prob. 118QRTCh. 15 - Prob. 119QRTCh. 15 - Prob. 120QRTCh. 15 - Prob. 121QRTCh. 15 - Prob. 122QRTCh. 15 - You are given four different aqueous solutions and...Ch. 15 - Prob. 124QRTCh. 15 - Prob. 126QRTCh. 15 - Prob. 15.ACPCh. 15 - Prob. 15.BCP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A 0.0415 L volume of 0.11 M hypochlorous acid (HCIO), a weak acid with K₂ = 4.0x108, is titrated with 0.11 M potassium a hydroxide (KOH), a strong base. Determine the pH at the following points in the titration. (a) before any KOH has been added с (b) after 0.0058 L KOH has been added Indicate which point is the equivalence point. O a b Od (c) after 0.0415 L KOH has been addedarrow_forwardYou have 25.00 mL of a 0.100 M aqueous solution of the weak base (CH3)2NH (Kb = 7.40 x 10-4). This solution will be titrated with 0.100 M HCl. (a) How many mL of acid must be added to reach the equivalence point? (b) What is the pH of the solution before any acid is added? ( c) What is the pH of the solution after 10.00 mL of acid has been added? (d) What is the pH of the solution at the equivalence point of the titration? (e) What is the pH of the solution when 30.00 mL of acid has been added?arrow_forwardA buffer contains 0.010 mol of lactic acid (pKa = 3.86) and 0.050 mol of sodium lactate per liter. (a) Calculate the pH of the buffer. (b) Calculate thechange in pH when 5 mL of 0.5 M HCl is added to 1 L of the buffer. (c) What pH change would you expect if you added the same quantity of HCl to 1 L of pure water?arrow_forward
- Assume you titrate 20.0 mL of 0.11 M NH3 with 0.10 M HCl. (a) What is the pH of the NH3 solution before the titration begins? (b) What is the pH of the equivalence point? (c) What is the pH at the midpoint of the titration? (d) Which indicator would you suggest to detect the equivalence point? (e) Calculate the pH of the solution after adding 5.00, 11.0, 15.0, 20.0, 22.0, and 25.0 mL of the acid. Combine this information with that from (a) through (c) and plot the titration curve.arrow_forwardConsider the titration of 36.0 mL of 0.123 M ammonia with 0.0766 M HCl. (See the Acid-Base Table attached.) (a) How many mL of HCl are required to reach the equivalence point?57.8 mL(b) What is the pH at the equivalence point? 5.29(c) What is the pH of the solution after the addition of 17.2 mL of acid? (d) What is the pH of the solution after the addition of 84.3 mL of acid? (only need help witn c and d)arrow_forwardA 35.00-mL solution of 0.2500 M HF is titrated with a standardized 0.1762 M solution of NaOH at 25 °C. (a) What is the pH of the HF solution before titrant is added? (b) How many milliliters of titrant are required to reach the equivalence point? mL (c) What is the pH at 0.50 mL before the equivalence point? (d) What is the pH at the equivalence point? (e) What is the pH at 0.50 mL after the equivalence point?arrow_forward
- A 5.296 g sample of a solid, weak, monoprotic acid is used to make a 100.0 mL solution. 30.00 mL of the resulting acid solution is then titrated with 0.09755 M NaOH. The pH after the addition of 21.00 mL of the base is 5.02, and the endpoint is reached after the addition of 46.38 mL of the base. (a) How many moles of acid were present in the 30.00 mL sample? 0.004524 mol(b) What is the molar mass of the acid?351.1 g/mol(c) What is the pKa of the acid? just need help with part Carrow_forwardA 5.145 g sample of a solid, weak, monoprotic acid is used to make a 100.0 mL solution. 27.00 mL of the resulting acid solution is then titrated with 0.09636 M NaOH. The pH after the addition of 16.00 mL of the base is 5.75, and the endpoint is reached after the addition of 45.85 mL of the base. (a) How many moles of acid were present in the 27.00 mL sample?4.42e-3 mol(b) What is the molar mass of the acid?314 g/mol(c) What is the pKa of the acid? (only confused on part c, answers for a and b are given)arrow_forward(b) Lead(II) hydroxide, Pb(OH)2 consists of lead(II) ion and hydroxide ion. Given that Kyp value of Pb(OH)2 is 4.0 × 10-20. (i) What is the pH needed for an aqueous solution of 7.5 x 10-13 M Pb2+ begin to precipitate as Pb(OH)2?arrow_forward
- (a) Sketch a pH vs base volume curve for a weak acid/strong base titration. (b) Identify which region of the curve is the equivalence point. (c) Assuming the titration is stopped exactly at the equivalence point, and that the acid's Ka value is 1.82 x 10-5, what is the pH at the equivalence point?arrow_forward1. 50.00ml of 2.000M ammonium nitrate is titrated with 0.800M NaOH. (a) What is the pH at the equivalence point? (b) What is the pH of the solution at the initial point? (c) What is the volume of NaOH required to react with all of the acid? (d) What is the pH of the solution after the addition of 175.00ml of the base? (e) What is the pH of the solution halfway to the equivalence point?arrow_forwardThe titration curve as shown is for the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH. The reaction can be represented as: CH3 CO2 H + OH− ⟶ CH3 CO2− + H2 O(a) What is the initial pH before any amount of the NaOH solution has been added? Ka = 1.8 × 10−5 for CH3CO2H. (b) Find the pH after 25.00 mL of the NaOH solution have been added.(c) Find the pH after 12.50 mL of the NaOH solution has been added.(d) Find the pH after 37.50 mL of the NaOH solution has been added.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY