Concept explainers
(a)
Interpretation:
The
Concept Introduction:
The dissociation constant of water,
(b)
Interpretation:
The
Concept Introduction:
Solubility product relates the solubility of a salt with the concentration of ions present in the salt. Solubility product holds a direct relation with the solubility of the salt. The solubility product is the ability of the solid to dissolve in aqueous solution. The more the solubility product the more the solid dissolves in solution. It is denoted as
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Chemistry: The Molecular Science
- Phosphate ions are abundant in cells, both as the ions themselves and as important substituents on organic molecules. Most importantly, the pKa for the H2PO4 ion is 7.20, which is very close to the normal pH in the body. H2PO4(aq) + H2O() H3O+(aq) + HPO42(aq) 1. What should the ratio [HPO42]/[H2PO4] be to control the pH at 7.40?arrow_forwardAcrylic acid is used in the polymer industry in the production of acrylates. Its K, is 5.6 X 10“’. What is the pH of a 0.11 M solution of acrylic acid, CH2CHCOOH?arrow_forwardWhat are the major species in solution after NaHSO4 is dissolved in water? What happens to the pH of the solution as more NaHSO4 is added? Why? Would the results vary if baking soda (NaHCO3) were used instead?arrow_forward
- The text describes zinc hydroxide as an amphoteric hydroxide, so Zn(OH)2 is soluble in basic solution. What is the molar solubility of Zn(OH)2 in 1.00 M NaOH? What is the pH of the equilibrium solution?arrow_forwardAn important component of blood is the buffer combination of dihydrogen phosphate ion and the hydrogen phosphate ion. Consider blood with a pH of 7.44. a What is the ratio of [H2PO4] to [HPO42]? b What does the pH become if 25% of the hydrogen phosphate ions are converted to dihydrogen phosphate ion? c What does the pH become if 15% of the dihydrogen phosphate ions are converted to hydrogen phosphate ions?arrow_forwardA 0.018 M solution of salicylic acid, HOC6H4CO2H, has the same pH as 0.0038 M HNO3solution. (a) Write an equation for the ionization of salicylic acid in aqueous solution. (Assume only the –CO2H portion of the molecule ionizes.) (b) What is the pH of solution containing 0.018 M salicylic acid? (c) Calculate the Ka of salicylic acid.arrow_forward
- You are given two glasses of water that have different temperatures. The temperature of the first glass is at 298 K, while the second glass has a temperature of 303 K. It has been determined that the Kw value for the second glass of water is 1.47 x 10-¹4. Which of the following statements is true? (a) The pH of the room temperature glass is higher, but both glasses have the same acidity. (b) The room temperature glass of water has a higher pH, and is more basic than the other glass of water. (c) Both glasses of water are neutral, so both will have a pH of 7.00. (d) The room temperature water has a lower pH, so is more acidic. (e) The warmer glass of water has a lower pH, and is more acidic than the other glass of water.arrow_forward33. Consider a buffer solution that contains 0.45 M HCOOH and 0.55 M NaHCOO. Note that the Ka for formic acid (HCOOH) is 1.8 x 104. (a) Calculate the pH of this buffer solution. pH = (b) Write the net ionic chemical equation that occurs when potassium hydroxide (KOH) (MW of KOH = 56.1 g/mol) is added to the buffer. (c) If 0.260 g of solid KOH is added to 250. mL of this buffer solution, what is the resulting pH of the solution? New pH =arrow_forward4. How does the pH of each of the following solutions change when 5.0 mL of 1.0 M NaOH (a strong base) is added? Fill in the table. Give your answers with 2 decimals. Initial pH Final pH after adding NaOH Solution (a) 100.0 ml water (b) (c) 100.0 mL 0.150 M HNO2 (a weak acid) (Given: Ka = 4.5 × 10-4) 100.0 mL solution of 0.150 M HNO2 and 0.100 M NaNO₂arrow_forward
- Calculate the change in pH when 6.00 mL of 0.100 M HCl(aq) is added to 100.0 mL of a buffer solution that is 0.100 M in NH3(aq) and 0.100 M in NH4Cl(aq). Consult the table of ionization constants as needed. ΔpH=? Calculate the change in pH when 6.00 mL of 0.100 M NaOH is added to the original buffer solution. ΔpH=?arrow_forwardWhat is the molarity of a solution made by dissolving 3.4 g of Ba(OH)2 in enough water tomake 450. mL of solution? Assume that Ba(OH)2 dissociates completely in water to Ba2+ andOH¯ ions. What is the pH of the solution?arrow_forwardGiven that Ka’s for hydrofluoric acid (HF) and boric acid (H3BO3) are 6.3 × 10^–4 and 5.4 × 10^–10, respectively, calculate the pH of the following solutions: (a) The mixture from adding 50 mL 0.2 M HF to 50 mL 0.5 M sodium borate (NaH2BO3). (b) The mixture from adding an additional 150 mL 0.2 M HF to the solution in (a), i.e., a total of 200 mL 0.2 M HF was added to 50 mL 0.5 M NaH2BO3.arrow_forward
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