Nitric oxide emitted from the engines of supersonic aircraft can contribute to the destruction of stratospheric ozone: N O ( g ) + O 3 ( g ) ⇄ k r k f N O 2 ( g ) + O 2 ( g ) Nitric oxide emissions from supersonic aircraft can contribute to destruction ofthe ozone layer. This reaction is highly exothermic ( Δ H = − 201 k j ) , and its equilibrium constant k c is 3.4 × 10 34 at 300 K. (a) Which rate constant is larger? k f o r k r (b) The value of k f at 300 K is 8.5 × 10 6 M − 1 s − 1 . What is the value of k r at the same temperature?
Nitric oxide emitted from the engines of supersonic aircraft can contribute to the destruction of stratospheric ozone: N O ( g ) + O 3 ( g ) ⇄ k r k f N O 2 ( g ) + O 2 ( g ) Nitric oxide emissions from supersonic aircraft can contribute to destruction ofthe ozone layer. This reaction is highly exothermic ( Δ H = − 201 k j ) , and its equilibrium constant k c is 3.4 × 10 34 at 300 K. (a) Which rate constant is larger? k f o r k r (b) The value of k f at 300 K is 8.5 × 10 6 M − 1 s − 1 . What is the value of k r at the same temperature?
Solution Summary: The author explains the equation for the rate of the reaction for forwarding and reverse reactions.
Nitric oxide emitted from the engines of supersonic aircraft can contribute to the destruction of stratospheric ozone:
N
O
(
g
)
+
O
3
(
g
)
⇄
k
r
k
f
N
O
2
(
g
)
+
O
2
(
g
)
Nitric oxide emissions from supersonic aircraft can contribute to destruction ofthe ozone layer. This reaction is highly exothermic
(
Δ
H
=
−
201
k
j
)
, and its equilibrium constant
k
c
is
3.4
×
10
34
at 300 K. (a) Which rate constant is larger?
k
f
o
r
k
r
(b) The value of
k
f
at 300 K is
8.5
×
10
6
M
−
1
s
−
1
. What is the value of
k
r
at the same temperature?
3. Put the following species in order of increasing bond length by using molecular orbital diagrams and
calculating their bond orders: F2, F2, F2+
Molecular Orbital Diagram
F2
F2
F2+
Bond Order
Shortest bond:
Longest bond
3. Put the following species in order of increasing bond length by using molecular orbital diagrams and
calculating their bond orders: F2, F2, F2+
Molecular Orbital Diagram
F2
F2
F2+
Bond Order
4. The superoxide ion, Oz, plays an important role in the ageing processes that take place in organisms.
Judge whether Oz is likely to have larger or smaller dissociation energy than 02.
Molecular Orbital Diagram
02
02
Does O2 have larger or smaller dissociation energy?:
Bond Order
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell