(a) Interpretation: The value of K c and K p in the given reaction needs to be determined. Concept introduction: For the equilibrium reaction, the expression for the equilibrium constant is the ratio of concentration of product to reactant raised to their stoichiometric coefficients. The relation between equilibrium constant with respect to concentration and pressure can be represented as follows: K P =K c × ( RT ) n Here, n is change in number of moles of gases that is product-reactant, R is Universal gas constant and T is temperature.
(a) Interpretation: The value of K c and K p in the given reaction needs to be determined. Concept introduction: For the equilibrium reaction, the expression for the equilibrium constant is the ratio of concentration of product to reactant raised to their stoichiometric coefficients. The relation between equilibrium constant with respect to concentration and pressure can be represented as follows: K P =K c × ( RT ) n Here, n is change in number of moles of gases that is product-reactant, R is Universal gas constant and T is temperature.
Solution Summary: The author explains that the equilibrium constant is the ratio of concentration of product to reactant raised to their stoichiometric coefficients.
Definition Definition Number that is expressed before molecules, ions, and atoms such that it balances out the number of components present on either section of the equation in a chemical reaction. Stoichiometric coefficients can be a fraction or a whole number and are useful in determining the mole ratio among the reactants and products. In any equalized chemical equation, the number of components on either side of the equation will be the same.
Chapter 15, Problem 15.103SP
Interpretation Introduction
(a)
Interpretation:
The value of Kc and Kp in the given reaction needs to be determined.
Concept introduction:
For the equilibrium reaction, the expression for the equilibrium constant is the ratio of concentration of product to reactant raised to their stoichiometric coefficients.
The relation between equilibrium constant with respect to concentration and pressure can be represented as follows:
KP=Kc×(RT)n
Here, n is change in number of moles of gases that is product-reactant, R is Universal gas constant and T is temperature.
Interpretation Introduction
(b)
Interpretation:
The concentrations needs to be determined, when the mixture reaches the equilibrium.
Concept introduction:
For the equilibrium reaction, the expression for the equilibrium constant is the ratio of concentration of product to reactant raised to their stoichiometric coefficients.
MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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