Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 14.7, Problem 14P
Interpretation Introduction
Interpretation:
The concentration of a vitamin A sample with absorbance at 325 nm (A) = 0.735 in a cell with path length of 1.00 cm is to be calculated if its ε value is 50100.
Concept introduction:
The molar absorptivity, ε, is given by 
where A is absorbance, C is the concentration of the solution in moles/lit and l is the sample path length in cm.
To calculate:
The concentration of a vitamin A sample with absorbance at 325 nm (A) = 0.735 in a cell with path length of 1.00 cm if its ε value is 50100.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Guanosine has a maximum absorbance of 275 nm. ϵ275= 8400M−1cm−1 and the path length is 1 cm. Using a spectrophotometer, you find the that A275=0.70. What is the concentration of guanosine?
A solution of a specific vitamin has λmax = 324 nm and a molar absorptivity (ϵ) of 0.081 L·mol-1cm-1. The concentration of the solution is 1.6 M. Calculate the absorbance of the vitamin solution at 324 nm (sample pathlength = 1.00 cm)
A solution of a specific vitamin has a åmax of 245 nm and a concentration of 4.15 x 10-M. The absorbance of the solution at
245 nm is A = 0.145. What is the molar absorptivity of the vitamin at 245 nm ? A sample path length is 1.00 cm.
molar absorptivity:
L mol-'cm-!
Chapter 14 Solutions
Organic Chemistry
Ch. 14.1 - Prob. 1PCh. 14.2 - Give the structures of both 1, 2 and 1, 4 adducts...Ch. 14.2 - Prob. 3PCh. 14.2 - Give the structures of both 1, 2 and 1, 4 adducts...Ch. 14.3 - Prob. 5PCh. 14.3 - Prob. 6PCh. 14.5 - Predict the product of the following Diels–Alder...Ch. 14.5 - Prob. 8PCh. 14.5 - Which of the following dienes have an s-cis...Ch. 14.5 - Predict the product of the following Diels–Alder...
Ch. 14.6 - Prob. 11PCh. 14.6 - Prob. 12PCh. 14.7 - Prob. 13PCh. 14.7 - Prob. 14PCh. 14.8 - Which of the following compounds would you expect...Ch. 14.SE - Prob. 16VCCh. 14.SE - Show the product of the Diels–Alder reaction of...Ch. 14.SE - Prob. 18VCCh. 14.SE - Prob. 19VCCh. 14.SE - Prob. 20MPCh. 14.SE - Prob. 21MPCh. 14.SE - In light of your answer to Problem 14-21 propose...Ch. 14.SE - Luminol, which is used by forensic scientists to...Ch. 14.SE - Prob. 24MPCh. 14.SE - Give IUPAC names for the following compounds:Ch. 14.SE - Prob. 26APCh. 14.SE - Prob. 27APCh. 14.SE - Electrophilic addition of Br2 to isoprene...Ch. 14.SE - Prob. 29APCh. 14.SE - Prob. 30APCh. 14.SE - Predict the products of the following...Ch. 14.SE - 2,3-Di-tert-butyl-1,3-butadiene does not undergo...Ch. 14.SE - Prob. 33APCh. 14.SE - Prob. 34APCh. 14.SE - Prob. 35APCh. 14.SE - Prob. 36APCh. 14.SE - Rank the following dienophiles in order of their...Ch. 14.SE - Prob. 38APCh. 14.SE - Prob. 39APCh. 14.SE - Prob. 40APCh. 14.SE - Although the Diels–Alder reaction generally...Ch. 14.SE - Prob. 42APCh. 14.SE - Tires whose sidewalls are made of natural rubber...Ch. 14.SE - Prob. 44APCh. 14.SE - Prob. 45APCh. 14.SE - Prob. 46APCh. 14.SE - Would you expect allene, H2C = C = CH2, to show a...Ch. 14.SE - The following ultraviolet absorption maxima have...Ch. 14.SE - Prob. 49APCh. 14.SE - -Ocimene is a pleasant-smelling hydrocarbon found...Ch. 14.SE - Draw the resonance forms that result when the...Ch. 14.SE - Prob. 52APCh. 14.SE - Treatment of 3,4-dibromohexane with strong base...Ch. 14.SE - Prob. 54APCh. 14.SE - Prob. 55APCh. 14.SE - Prob. 56APCh. 14.SE - Prob. 57APCh. 14.SE - Prob. 58APCh. 14.SE - Hydrocarbon A, C10H14, has a UV absorption at...Ch. 14.SE - Prob. 60APCh. 14.SE - Prob. 61APCh. 14.SE - Prob. 62APCh. 14.SE - Prob. 63APCh. 14.SE - Prob. 64APCh. 14.SE - The double bond of an enamine (alkene + amine) is...Ch. 14.SE - Prob. 66AP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Q3) A solution of Tryptophan has an absorbance at 280 nm of 0.25 in a 0.5 cm length cuvette. Given the absorbance coefficient of Tryptophan is 6.4 × 103 L Mol-1 cm-1. What is the concentration of solution?arrow_forwardA specific steroid has a Amax of 251 nm and a molar absorptivity e of 11, 500 L mol-¹ cm-¹. What is the concentration of the compound in a solution whose absorbance at 251 nm is A = 0.075 with a sample pathlength of 1.00 cm? concentration: Marrow_forwardA specific steroid has a λmax of 249 nm and a molar absorptivity ε of 11,500 L mol−1 cm–1. What is the concentration of the compound in a solution whose absorbance at 249 nm is A = 0.050 with a sample pathlength of 1.00 cm?arrow_forward
- A solution prepared by dissolving 25.8 mg of benzene (78.11 g/mol) in hexane (86.16 g/mol) and diluting to 250 mL had an absorption peak at 256 nm and an absorbance of 0.266 in a 1.000-cm cell. What is the concentration of benzene solution? O 1.20x10-3 M O 1.32x10-3 M O 1.32 M O 1.20 Marrow_forwardSo Please don't provide the handwriting solutionarrow_forwardI have 4 Questuion Q1: find the A , T , T% of a 2.4X10-3 mol L-1 solution of a substance whose molar absorptivity is 313 L M-1 cm -1 at 520 nm when measured in a cell of 2.00 cm pathlength ؟ Q2: A sample in a 1 cm cuvette transmits 79% of light at 280 nm , what is the absorbance ? if the molar extinction coefficient is 2.0 M-1 cm-1 , what is the concentration of the sample ? Q3 : the aspirin an analgesic form complex with metal ion which has a molar absorpitvity of 8000 L M-1 cm-1 at ( lenada max 435 nm ) . calculate the absorbance of 6.77 X 10-5 M solution of the complex measured in a 1.00 cm cell at 435 nm ? Q4 :Find the A and T% of a 6.5X10-4 Mol L-1 solution of a drug ( molecular weigth 200 ) whose absorpitvity is 0.026 L cm-1 g-1 at 520 nm when measured in a cell of 2.00 cm pathlength ?arrow_forward
- What is the concentration of a tyrosine solution when the absorbance at 280 nm is 1.5 using a 1 cm cuvette and the molar extinction coefficient is 1405 L/mol·cm?arrow_forwardA solution with %T = 75.9% has an absorbance equal to: A = log (1 T) T= (% T 100)arrow_forwardGiven: You mix together 3 mL of Al3+ (3.00 x 10-5 M) and 3 mL of xylenol orange (5.00 x 10-5 M). The absorbance at room temperature is 0.1 and the absorbance at 65oC is 0.35. a. What is the concentration of AlQ- at 65 degrees Celcius?arrow_forward
- an absorbance of a solution with a pathlength of 1.00 cm is 0.544 and concentration is 1.40x10^ ^ -3 M , what is its molar absorptivity?arrow_forwardIn a pharmaceutical industry a drug Paracetamol (151.163 g/mol) is determined in a sample. A 0.0315 g samples was reacted with methanol and diluted the solution to 1 L. the solution λ max at 243 nm (ε=2.6×104 cm-1 mol-1 L). The solution exhibits an absorbance of 0.642 in a 2 cm cell. Calculate the percentage paracetamol in the sample.arrow_forwardWhat is the concentration of a solution with an absorbance at 600 nm (A600) of 0.8 that has an extinction coefficient of 2.0 L/(mmol cm) (assume pathlength is 1 cm and provide your answer should in units of mM, but do NOT write the mM).arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Macroscale and Microscale Organic Experiments
Chemistry
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Brooks Cole
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning