The number of isomeric ethers that exist when the R groups present in the ether are C 2 and C 2 alkyl groups has to be given. Concept Introduction: Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula. Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism. If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group , but they differ in the connectivity between the atoms in the molecule.

Question

9. Assign an IUPAC name to each of the following compounds. 2. a. CH3-C-O-C-CH2-CH, b. CH3-CH2-CH-CH-C-CI L. C. CH3-CH-CH-C-Cl ČH3 CH3 d. CH3-CH-C-0-C-H Draw the structures of the esters formed by reacting the following substances 1 molecule methanol and 1 molecule phosphoric acid 2 molecules methanol and 1 molecule phosphoric acid 1 molecule methanol and 1 molecule nitric acid 1 molecule ethylene glycol and 2 molecules of nitric acid 0. A. В. C, D.

Answer 1

Question

Chapter 14, Problem 14.116EP

(a)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C2 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(b)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C3 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 cycloalkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

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9. Assign an IUPAC name to each of the following compounds. 2. a. CH3-C-O-C-CH2-CH, b. CH3-CH2-CH-CH-C-CI L. C. CH3-CH-CH-C-Cl ČH3 CH3 d. CH3-CH-C-0-C-H Draw the structures of the esters formed by reacting the following substances 1 molecule methanol and 1 molecule phosphoric acid 2 molecules methanol and 1 molecule phosphoric acid 1 molecule methanol and 1 molecule nitric acid 1 molecule ethylene glycol and 2 molecules of nitric acid 0. A. В. C, D.

8. Assign an IUPAC name to each of the following ethers. a. H2 H2 H3C C-O-C-CH3

Please explain the chosen letter. Which is NOT a physical property of alcohols or phenols? a. Phenols are generally only slightly soluble in water. b. The solubilities of normal primary alcohols in water decrease with increasing molecular weight. c. The hydroxyl group of an alcohol is nonpolar. d. Due to hydrogen bonding, boiling points of alcohols are much higher than those of corresponding alkanes.

Answer 2

Question

Chapter 14, Problem 14.116EP

(a)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C2 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(b)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C3 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 cycloalkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

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Answer 3

Question

Chapter 14, Problem 14.116EP

(a)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C2 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(b)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C3 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 cycloalkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

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Answer 4

Question

Chapter 14, Problem 14.116EP

(a)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C2 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(b)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C3 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 cycloalkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

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Answer 5

Chapter 14, Problem 14.116EP

(a)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C2 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(b)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C3 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 cycloalkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 6

Chapter 14, Problem 14.116EP

(a)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C2 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 7

Chapter 14, Problem 14.116EP

(a)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C2 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C3 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C2 and C3 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 alkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 cycloalkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The number of isomeric ethers that exist when the R groups present in the ether are C4 and C4 cycloalkyl groups has to be given.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. These isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Answer 14

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Answer 25

Ch. 14.1 - Prob. 1QQ Ch. 14.1 - Prob. 2QQ Ch. 14.2 - Prob. 1QQ Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Prob. 3QQ Ch. 14.3 - Prob. 1QQ Ch. 14.3 - Prob. 2QQ Ch. 14.3 - Prob. 3QQ Ch. 14.3 - Prob. 4QQ Ch. 14.4 - Prob. 1QQ

Solution Summary: The author explains that organic compounds are represented shortly by the molecular formula and structural formula. Constitutional isomerism is possible in ether.

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