The correct IUPAC name for the given compound has to be chosen from the given options. Concept Introduction: IUPAC rules for naming alcohols that contain single hydroxyl group: Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”. The numbering has to be given so that the hydroxyl group gets the least numbering. Name and location of any other substituent present in the chain has to be identified. If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering. Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group. IUPAC rules for naming alcohols that contain more than one hydroxyl group: The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

Question

Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

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Question

Chapter 14.3, Problem 4QQ

Interpretation Introduction

Interpretation:

The correct IUPAC name for the given compound has to be chosen from the given options.

Concept Introduction:

IUPAC rules for naming alcohols that contain single hydroxyl group:

Longest carbon chain has to be identified that contains hydroxyl group also. The chain name is obtained by replacing the letter “-e” in alkane with “-ol”.

The numbering has to be given so that the hydroxyl group gets the least numbering.

Name and location of any other substituent present in the chain has to be identified.

If in a ring the hydroxyl group is present, then that carbon is numbered 1 and the numbering then proceeds counterclockwise or clockwise in a way that substituents present if any gets the least numbering.

Hydroxyl group as a substituent in a molecule is named as hydroxy group rather than hydroxyl group.

IUPAC rules for naming alcohols that contain more than one hydroxyl group:

The same rules said above is followed but the prefix di-, tri-, tetra etc is added corresponding to the number of hydroxyl groups that is present.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

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