The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn. Concept Introduction: Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene . Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature ( 140 °C ) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Question

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

Answer 1

Question

Chapter 14, Problem 14.56EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(b)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

Assign all the protons

PROPOSE REACTION MECHANISM FOR ACID-CATALYZED REACTION OF 3-PENTANONE WITH DIMETHYLAMINE

Answer 2

Question

Chapter 14, Problem 14.56EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(b)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

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Answer 3

Question

Chapter 14, Problem 14.56EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(b)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

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Answer 4

Question

Chapter 14, Problem 14.56EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(b)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

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Answer 5

Chapter 14, Problem 14.56EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(b)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 6

Chapter 14, Problem 14.56EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 7

Chapter 14, Problem 14.56EP

(a)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 12

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 13

(c)

Interpretation Introduction

Interpretation:

The predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

Concept Introduction:

Dehydration reaction is the loss of water from a single reactant. Alcohol undergoes dehydration reaction to form alkene. Sulfuric acid acts as a catalyst for hydration of alkene at room temperature. The same sulfuric acid acts as a dehydrating agent when treated with alcohol at high temperature. If the reaction is carried out at a lower temperature, the loss of water molecule takes place from two molecule of reactant. This results in the formation of ether. Primary alcohol when treated with sulfuric acid at lower temperature (140 °C) gives ether as the product while secondary and primary alcohol gives alkene as the main product in good yield.

Answer 14

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Answer 25

Ch. 14.1 - Prob. 1QQ Ch. 14.1 - Prob. 2QQ Ch. 14.2 - Prob. 1QQ Ch. 14.2 - Prob. 2QQ Ch. 14.2 - Prob. 3QQ Ch. 14.3 - Prob. 1QQ Ch. 14.3 - Prob. 2QQ Ch. 14.3 - Prob. 3QQ Ch. 14.3 - Prob. 4QQ Ch. 14.4 - Prob. 1QQ

Solution Summary: The author explains that the predominant organic product structure in the given reaction that involves alcohol as reactant has to be drawn.

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Chapter 14 Solutions