Interpretation:
The reason for representation of coefficients in balanced chemical equation with molar amounts along with relative volumes is to be justified.
Concept introduction:
This is based on
According to it,

Answer to Problem 82A
Because
Explanation of Solution
It is given by
Equal volumes of all gases at same temperature and pressure contain equal number of molecules or moles.
Therefore coefficients in balanced chemical equation represent not only molar amounts but also relative volumes for gases
Chapter 13 Solutions
Chemistry: Matter and Change
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