
World of Chemistry
7th Edition
ISBN: 9780618562763
Author: Steven S. Zumdahl
Publisher: Houghton Mifflin College Div
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Question
Chapter 13, Problem 54A
Interpretation Introduction
Interpretation: The reason of gas behaving non-ideally on decreasing the volume of gas is to be discussed.
Concept introduction:
This is based on kinetic theory of gases.
Expert Solution & Answer

Answer to Problem 54A
When volume of a gas is decreased, the volume occupied by a gas molecule becomes measurable. So, gas deviates from ideal behaviour.
Explanation of Solution
According to kinetic molecular theory, a gas which is ideal follows:
- Volume occupied by a molecule should be negligible as compared to total volume of gas.
- There should be no attractive forces between the gas molecules.
So, when volume is decreased, the gas particles come closer and attractions between the particles increases. So, it behaves no-ideally.
Conclusion
Thus gases deviate from ideal behaviour on decreasing the volume of the gas.
Chapter 13 Solutions
World of Chemistry
Ch. 13.1 - Prob. 1RQCh. 13.1 - Prob. 2RQCh. 13.1 - Prob. 3RQCh. 13.1 - Prob. 4RQCh. 13.1 - Prob. 5RQCh. 13.1 - Prob. 6RQCh. 13.1 - Prob. 7RQCh. 13.2 - Prob. 1RQCh. 13.2 - Prob. 2RQCh. 13.2 - Prob. 3RQ
Ch. 13.2 - Prob. 4RQCh. 13.2 - Prob. 5RQCh. 13.2 - Prob. 6RQCh. 13.2 - Prob. 7RQCh. 13.2 - Prob. 8RQCh. 13.3 - Prob. 1RQCh. 13.3 - Prob. 2RQCh. 13.3 - Prob. 3RQCh. 13.3 - Prob. 4RQCh. 13.3 - Prob. 5RQCh. 13 - Prob. 1ACh. 13 - Prob. 2ACh. 13 - Prob. 3ACh. 13 - Prob. 4ACh. 13 - Prob. 5ACh. 13 - Prob. 6ACh. 13 - Prob. 7ACh. 13 - Prob. 8ACh. 13 - Prob. 9ACh. 13 - Prob. 10ACh. 13 - Prob. 11ACh. 13 - Prob. 12ACh. 13 - Prob. 13ACh. 13 - Prob. 14ACh. 13 - Prob. 15ACh. 13 - Prob. 16ACh. 13 - Prob. 17ACh. 13 - Prob. 18ACh. 13 - Prob. 19ACh. 13 - Prob. 20ACh. 13 - Prob. 21ACh. 13 - Prob. 22ACh. 13 - Prob. 23ACh. 13 - Prob. 24ACh. 13 - Prob. 25ACh. 13 - Prob. 26ACh. 13 - Prob. 27ACh. 13 - Prob. 28ACh. 13 - Prob. 29ACh. 13 - Prob. 30ACh. 13 - Prob. 31ACh. 13 - Prob. 32ACh. 13 - Prob. 33ACh. 13 - Prob. 34ACh. 13 - Prob. 35ACh. 13 - Prob. 36ACh. 13 - Prob. 37ACh. 13 - Prob. 38ACh. 13 - Prob. 39ACh. 13 - Prob. 40ACh. 13 - Prob. 41ACh. 13 - Prob. 42ACh. 13 - Prob. 43ACh. 13 - Prob. 44ACh. 13 - Prob. 45ACh. 13 - Prob. 46ACh. 13 - Prob. 47ACh. 13 - Prob. 48ACh. 13 - Prob. 49ACh. 13 - Prob. 50ACh. 13 - Prob. 51ACh. 13 - Prob. 52ACh. 13 - Prob. 53ACh. 13 - Prob. 54ACh. 13 - Prob. 55ACh. 13 - Prob. 56ACh. 13 - Prob. 57ACh. 13 - Prob. 58ACh. 13 - Prob. 59ACh. 13 - Prob. 60ACh. 13 - Prob. 61ACh. 13 - Prob. 62ACh. 13 - Prob. 63ACh. 13 - Prob. 64ACh. 13 - Prob. 65ACh. 13 - Prob. 66ACh. 13 - Prob. 67ACh. 13 - Prob. 68ACh. 13 - Prob. 69ACh. 13 - Prob. 70ACh. 13 - Prob. 1STPCh. 13 - Prob. 2STPCh. 13 - Prob. 3STPCh. 13 - Prob. 4STPCh. 13 - Prob. 5STPCh. 13 - Prob. 6STPCh. 13 - Prob. 7STPCh. 13 - Prob. 8STPCh. 13 - Prob. 9STPCh. 13 - Prob. 10STP
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