(a) Interpretation: The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written. Concept Introduction: Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene , the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

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Answer 1

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 13, Problem 13.106P

Interpretation Introduction

(a)

Interpretation:

The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(b)

Interpretation:

The name that corresponds to the PET should be given. The functional groups in PET should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(c)

Interpretation:

The name that corresponds to the PP should be given. The functional groups in PP should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

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1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)

Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Propose a synthesis pathway for the following transformations. b) c) d)

Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 13, Problem 13.106P

Interpretation Introduction

(a)

Interpretation:

The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(b)

Interpretation:

The name that corresponds to the PET should be given. The functional groups in PET should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(c)

Interpretation:

The name that corresponds to the PP should be given. The functional groups in PP should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 13, Problem 13.106P

Interpretation Introduction

(a)

Interpretation:

The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(b)

Interpretation:

The name that corresponds to the PET should be given. The functional groups in PET should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(c)

Interpretation:

The name that corresponds to the PP should be given. The functional groups in PP should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 13, Problem 13.106P

Interpretation Introduction

(a)

Interpretation:

The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(b)

Interpretation:

The name that corresponds to the PET should be given. The functional groups in PET should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(c)

Interpretation:

The name that corresponds to the PP should be given. The functional groups in PP should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

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Answer 5

Chapter 13, Problem 13.106P

Interpretation Introduction

(a)

Interpretation:

The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(b)

Interpretation:

The name that corresponds to the PET should be given. The functional groups in PET should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Interpretation Introduction

(c)

Interpretation:

The name that corresponds to the PP should be given. The functional groups in PP should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Answer 6

Chapter 13, Problem 13.106P

Interpretation Introduction

(a)

Interpretation:

The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Answer 7

Chapter 13, Problem 13.106P

Interpretation Introduction

(a)

Interpretation:

The name that corresponds to the LDPE should be given. The functional groups in LDPE should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The name that corresponds to the PET should be given. The functional groups in PET should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The name that corresponds to the PET should be given. The functional groups in PET should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The name that corresponds to the PP should be given. The functional groups in PP should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The name that corresponds to the PP should be given. The functional groups in PP should be identified. One fact about this compound should be written.

Concept Introduction:

Polymers are large molecules which are composed of many repeating units, known as monomers. The monomers are covalently bonded together. When polymer is made from an alkene, the weaker pi bond is broken and new carbon − carbon single bond is formed with another monomer.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.2P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.4P Ch. 13.2 - Prob. 13.5P Ch. 13.2 - Prob. 13.6P Ch. 13.3 - Prob. 13.7P Ch. 13.3 - Prob. 13.8P Ch. 13.3 - Prob. 13.9P Ch. 13.3 - Prob. 13.10P

Solution Summary: The author explains that the name that corresponds to the LDPE should be given and the functional groups in the compound identified.

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Chapter 13 Solutions